Disposable article providing improved management of bodily exudates

ABSTRACT

A disposable article adapted to receive bodily exudates which provides improved management of such bodily exudates by including an effective amount of one or more agents which act to modify the physical properties of feces or other bodily wastes which may be deposited in the article, or by including one or more compositions such as the aforesaid one or more agents which enhance the removability of bodily waste, such as feces, from the skin of the article&#39;s wearer.

CROSS REFERENCE

This is a continuation-in-part of under 35 U.S.C. §120 of patentapplication Ser. No. 09/107,561, filed Jun. 29, 1998, now U.S. Pat. No.6,149,636; Ser. No. 09/106,225, filed Jun. 29, 1998 now U.S. Pat. No.6,186,991; and Ser. No. 08/970,508, filed Nov. 14, 1997 now U.S. Pat.No. 5,957,906; and claims priority to Provisional Application Ser. Nos.60/091,076, filed Jun. 29, 1998 and 60/090,993.

FIELD OF THE INVENTION

The present invention relates to disposable articles which receive(i.e., which absorb and/or contain) bodily exudates, includingdisposable absorbent articles such as diapers, adult incontinenceproducts, sanitary napkins, disposable bodily waste-receiving articlessuch as waste or colostomy bags, and the like. More particularly, theinvention relates to disposable articles which provide improvedmanagement of bodily exudates by including one or more agents which actto modify the physical properties of feces or other bodily wastes whichmay be deposited in the article, or by including one or morecompositions such as the aforesaid agents which enhance the removabilityof bodily waste, such as feces, from the skin of the article's wearer.

BACKGROUND OF THE INVENTION

The major function of absorbent articles such as diapers, adultincontinence briefs, sanitary napkins and other disposable articles forreceiving body exudates is to prevent such body exudates from soiling,wetting, or otherwise contaminating clothing or other articles, such asbedding, that may come in contact with the wearer. In recent years,disposable diapers, such as those disclosed in U.S. Pat. No. 5,151,092issued to Buell et al., have become very popular and have generallyreplaced durable cloth absorbent articles because of their convenienceand reliability. However, despite the effectiveness of such disposableabsorbent articles, body exudates often still leak or are stored in thearticle such that the exudates soil and/or irritate the skin of thewearer. Additionally, body exudates often adhere aggressively to skin,increasing the difficulty of cleaning and increasing the likelihood ofchronic residual contamination. The fundamental causes of these, andother key problems with absorbent articles of the art lie in themobility under applied shear stress and adhesiveness of the feces.

The undesirable effects of leakage and/or improper containment,difficult cleanup, and/or residual skin contamination are especiallyevident with regard to fecal matter deposited in the article. Fecescontained in the article which comes in contact with the wearer, orwhich is left on the skin after attempts at cleanup, can harm the skinof the wearer over time. Feces leaking from the article almostinvariably presents unpleasant, messy cleanups of not only the wearer,but also of clothing or other objects that may come in contact with thewearer. Thus, several attempts have been made to add features toabsorbent articles such as barriers, pockets, spacers, transversebarriers, apertured topsheets and the like to limit the movement of thefecal material across the topsheet and/or to better confine the fecalmatter in the article. However, such attempts have been generallyunsuccessful because they fail to address the fundamental causes ofthese problems (i.e., the properties of feces) and, because of theircost and complexity. Further, many of the means for isolating orcontaining feces are directed to fecal material with certain physicalproperties (e.g., viscosity, free water content and particle size) andare not effective with exudates with physical properties outside a verysmall range.

U.S. Pat. No. 4,790,836 discloses a diaper including layer of medicatedpowder located between the absorbent core and a water-soluble film. Themedicated powder is used to promote drying of the infant's skin afterthe wearer wets the diaper. However, as shown in Tables II and VIII,below, embodiments such as disclosed in this patent do not function toprovide the feces management benefits of the present invention. It isalso known to coat a topsheet of a disposable absorbent article with alotion composition which can transfer to the skin of the wearer, such asdisclosed in U.S. Pat. Nos. 5,607,760, 5,609,587, 5,635,191 and5,643,588. However, such a lotion composition alone may not provide theenhanced fecal removability/cleaning benefit of the present invention.

Accordingly, it would be desirable to provide a disposable article withimproved bodily exudate management properties, such as a disposablearticle providing desirable feces modification and/or enhanced fecesremovability. Further, it would be advantageous to provide an economicaldisposable article with the ability to minimize the negative effects offeces or other viscous bodily waste on the wearer or the caregiver. Itwould also be advantageous to provide an article which is designed tochemically or physically interact with the feces and to change theproperties of the feces in order to improve acceptance of feces into thearticle and/or immobilization of the feces within the article and/orreduce the residual contamination of the wearer's skin with feces. Also,it would be desirable to provide an article having sufficient effectivecapacity and retention capability to store the physically or chemicallymodified feces safely and cleanly away from the wearer's skin and/orclothing throughout the expected time of use. It would be furtherdesirable to provide an article which enhances the efficacious cleanupof feces from the wearer's skin.

SUMMARY OF THE INVENTION

In order to help resolve at least some of the problems described aboveand otherwise found in the absorbent articles of the prior art, thepresent invention provides an article which provides improved managementof bodily exudates by including an agent which is available in aneffective concentration to physically or chemically modify some or allof the fecal material or other bodily exudates deposited in the articleor on the wearer's skin, or which includes one or more compositions,such as a feces modifying agent, for enhancing the removability andcleanup of feces or other bodily exudates from the wearer's skin. Themodification of the feces may improve acceptance and/or retention of theexudates within the article to reduce the spreading of fecal materialwithin the diaper and/or to reduce the tendency of the fecal material toadhere to the wearer's skin. The present invention may also provide anabsorbent article capable of accepting, storing and/or immobilizing theexudates in their modified form to reduce the likelihood that the wastewill migrate back toward the wearer's skin once the waste is imbibed bythe article. Accordingly, the absorbent article of the present inventionmay reduce the likelihood of harm to the wearer's skin and/or theinconvenience to the caregiver normally associated with bowel movementsor the excretion of other body exudates.

BRIEF DESCRIPTION OF THE DRAWINGS

While the specification concludes with claims particularly pointing outand distinctly claiming the subject matter which is regarded as thepresent invention, it is believed that the description will be betterunderstood from the following descriptions which are taken inconjunction with the accompanying drawings in which like designationsare used to designate substantially identical elements.

FIG. 1 is a plan view of an absorbent article embodiment of the presentinvention having portions cut away to reveal the underlying structure,the body-facing surface of the diaper facing the viewer.

FIG. 2 is a plan view of an absorbent article embodiment of the presentinvention having portions cut away to reveal the underlying structure,the body-facing surface of the diaper facing the viewer.

FIG. 3 is a cross sectional view of an absorbent article embodiment ofthe present invention taken through the section lines 3-3.

FIG. 4 is a cross sectional view of an alternative embodiment of anabsorbent article of the present invention.

FIG. 5 is a plan view of a sanitary napkin embodiment of the presentinvention with portions cut away to review the underlying structure.

FIG. 6 is a plan view of an alternative embodiment of the presentinvention.

FIG. 7 is an enlarged cross sectional view of an embodiment of thepresent invention.

FIG. 8 is a plan view of an absorbent article embodiment of the presentinvention having portions cut away to reveal the underlying structure,the body-facing surface of the diaper facing the viewer.

FIG. 9 is a schematic front view of an apparatus which may be used tomeasure Acceptance Under Pressure characteristics of certain structures.

FIG. 10 is a plan view of a piece of the apparatus shown in FIG. 9.

FIG. 11 is a plan view of an absorbent article embodiment of the presentinvention having portions cut away to reveal the underlying structure,the body-facing surface of the diaper facing the viewer.

FIG. 12 is a cross sectional view of a portion of an absorbent articleembodiment of the present invention taken through the section lines12-12 of FIG. 11, having additional portions of the article removed.

FIG. 13 is a plan view of an assembly which may be used in measuringWaste Contamination Area and Waste Contamination Mass characteristics.

FIG. 14 is a plan view of an assembly and apparatus which may be used inmeasuring Waste Contamination Area and Waste Contamination Masscharacteristics.

FIG. 15 is a plan view of an assembly and apparatus which may be used inmeasuring Waste Contamination Area and Waste Contamination Masscharacteristics.

FIG. 16 is a plan view of an assembly and apparatus which may be used inmeasuring Waste Contamination Area and Waste Contamination Masscharacteristics.

FIG. 17 is a plan view of an apparatus which may be used in measuringWaste Contamination Area and Waste Contamination Mass characteristics.

FIG. 18 is a side view of an apparatus which may be used in measuringWaste Contamination Area and Waste Contamination Mass characteristics.

FIG. 19 is a perspective view of an assembly and apparatus which may beused in measuring Waste Contamination Area and Waste Contamination Masscharacteristics.

FIG. 20 is a plan view of an assembly and apparatus which may be used inmeasuring Waste Contamination Area and Waste Contamination Masscharacteristics.

FIG. 21 is a perspective view of a waste bag embodiment of the presentinvention.

FIG. 22 is a perspective view of an absorbent article including a wastebag.

DETAILED DESCRIPTION OF THE INVENTION

As used herein, the term “absorbent article” refers to devices whichabsorb and contain body exudates, and more specifically, refers todevices which are placed against or in proximity to the body of thewearer to absorb and contain the various exudates discharged from thebody. The term “disposable” is used herein to describe articles whichgenerally are not intended to be laundered or otherwise restored orreused (i.e., they are intended to be discarded after a single use and,preferably, to be recycled, composted or otherwise disposed of in anenvironmentally compatible manner). (As used herein, the term “disposed”is used to mean that an element(s) of the diaper is formed (joined orpositioned) in a particular place or position as a unitary structurewith other elements of the diaper or as a separate element joined toanother element of the diaper. As used herein, the term “joined”encompasses configurations whereby an element is directly secured toanother element by affixing the element directly to the other element,and configurations whereby an element is indirectly secured to anotherelement by affixing the element to intermediate member(s) which in turnare affixed to the other element.) A “unitary” absorbent article refersto absorbent articles which are formed of separate parts united togetherto form a coordinated entity so that they do not require separatemanipulative parts like a separate holder and liner.

A preferred embodiment of an absorbent article of the present inventionis the unitary disposable absorbent article, diaper 20, shown in FIG. 1.(As used herein, the term “diaper” refers to an absorbent articlegenerally worn by infants and incontinent persons about the lowertorso.) However, the present invention is also applicable to otherabsorbent articles such as incontinence briefs, incontinenceundergarments, inserts including absorbent inserts, diaper holders andliners, feminine hygiene garments, wipes, mops, bandages and the like.The present invention is also applicable to absorbent or nonabsorbentfeces collection devices, such as waste or colostomy bags, which may forexample be separately applied to the wearer's perianal region.

FIG. 1 is a plan view of a diaper 20 of the present invention in aflat-out, state with portions of the structure being cut-away to moreclearly show the construction of the diaper 20. The portion of thediaper 20 which faces the wearer is oriented towards the viewer. Asshown in FIG. 1, the diaper 20 preferably comprises a liquid pervioustopsheet 24; a liquid impervious backsheet 26; an absorbent core 28,which is preferably positioned between at least a portion of thetopsheet 24 and the backsheet 26; side panels 30; elasticized leg cuffs32; an elastic waist feature 34; and a fastening system generallydesignated 40. Diaper 20 is shown in FIG. 1 to have a first waist region36, a second waist region 38 opposed to the first waist region 36 and acrotch region 37 located between the first waist region and the secondwaist region. The periphery of the diaper 20 is defined by the outeredges of the diaper 20 in which the longitudinal edges 50 run generallyparallel to the longitudinal centerline 100 of the diaper 20 and the endedges 52 run between the longitudinal edges 50 generally parallel to thelateral centerline 110 of the diaper 20. The chassis 22 of the diaper 20comprises the main body of the diaper 20.

The chassis 22 comprises at least a portion of the absorbent core 28 andpreferably an outer covering layer including the topsheet 24 and thebacksheet 26. If the absorbent article comprises a separate holder and aliner, the chassis 22 generally comprises the holder and the liner. (Forexample, the holder may comprise one or more layers of material to formthe outer cover of the article and the liner may comprise an absorbentassembly including a topsheet, a backsheet, and an absorbent core. Insuch cases, the holder and/or the liner may include a fastening elementwhich is used to hold the liner in place throughout the time of use.)For unitary absorbent articles, the chassis 22 comprises the mainstructure of the diaper with other features added to form the compositediaper structure.

While the topsheet 24, the backsheet 26, and the absorbent core 26 maybe assembled in a variety of well known configurations, preferred diaperconfigurations are described generally in U.S. Pat. No. 3,860,003entitled “Contractible Side Portions for Disposable Diaper” which issuedto Kenneth B. Buell on Jan. 14, 1975; U.S. Pat. No. 5,151,092 issued toBuell on Sep. 9, 1992; and U.S. Pat. No. 5,221,274 issued to Buell onJun. 22, 1993; and U.S. Pat. No. 5,554,145 entitled “Absorbent ArticleWith Multiple Zone Structural Elastic-Like Film Web Extensible WaistFeature” which issued to Roe et al. on Sep. 10, 1996; U.S. Pat. No.5,569,234 entitled “Disposable Pull-On Pant” which issued to Buell etal. on Oct. 29, 1996; and U.S. Pat. No. 5,580,411 entitled “Zero ScrapMethod For Manufacturing Side Panels For Absorbent Articles” whichissued to Nease et al. on December 3; each of which is incorporatedherein by reference.

The backsheet 26 is generally that portion of the diaper 20 positionedadjacent the garment facing surface 45 of the absorbent core 28 whichprevents the exudates absorbed and contained therein from soilingarticles which may contact the diaper 20, such as bedsheets andundergarments. In preferred embodiments, the backsheet 26 is imperviousto liquids (e.g., urine) and comprises a thin plastic film such as athermoplastic film having a thickness of about 0.012 mm (0.5 mil) toabout 0.051 mm (2.0 mils). Suitable backsheet films include thosemanufactured by Tredegar Industries Inc. of Terre Haute, Ind. and soldunder the trade names X15306, X10962 and X10964. Other suitablebacksheet materials may include breathable materials which permit vaporsto escape from the diaper 20 while still preventing exudates frompassing through the backsheet 26. Exemplary breathable materials mayinclude materials such as woven webs, nonwoven webs, composite materialssuch as film-coated nonwoven webs, microporous films such asmanufactured by Mitsui Toatsu Co., of Japan under the designation ESPOIRNO and by Exxon Chemical Co., of Bay City, Tex., under the designationEXXAIRE, and monolithic films such as manufactured by ClopayCorporation, Cincinnati, Ohio under the name HYTREL blend P18-3097. Somebreathable composite materials are described in greater detail in PCTApplication No. WO 95/16746, published on Jun. 22, 1995 in the name ofE. I. DuPont, U.S. Pat. No. 5,865,823 issued on Feb. 2, 1999 in the nameof Curro, and U.S. Pat. No. 5,571,096 issued to Dobrin et al. on Nov. 5,1996. Each of these references is hereby incorporated by referenceherein.

The backsheet 26, or any portion thereof, may be elastically extensiblein one or more directions. In one embodiment, the backsheet 26 maycomprise a structural elastic-like film (“SELF”) web as described inU.S. Pat. No. 5,518,801 entitled Web Materials Exhibiting Elastic-LikeBehavior, which issued to Chappell, et al. on May 21, 1996, which isincorporated herein by reference. In alternate embodiments, thebacksheet 26 may comprise elastomeric films, foams, strands, orcombinations of these or other suitable materials with nonwovens orsynthetic films.

The backsheet 26 may be joined to the topsheet 24, the absorbent core 28or any other element of the diaper 20 by any attachment means known inthe art. For example, the attachment means may include a uniformcontinuous layer of adhesive, a patterned layer of adhesive, or an arrayof separate lines, spirals, or spots of adhesive. Alternatively, theattachment means may comprise heat bonds, pressure bonds, ultrasonicbonds, dynamic mechanical bonds, or any other suitable attachment meansor combinations of these attachment means as are known in the art.

The topsheet 24 is preferably compliant, soft feeling, andnon-irritating to the wearer's skin. Further, at least a portion of thetopsheet 24 is liquid pervious, permitting liquids to readily penetratethrough its thickness. A suitable topsheet 24 may be manufactured from awide range of materials, such as porous foams; reticulated foams;apertured plastic films; or woven or nonwoven webs of natural fibers(e.g., wood or cotton fibers), synthetic fibers (e.g., polyester orpolypropylene fibers), or a combination of natural and synthetic fibers.If the topsheet includes fibers, the fibers may be spunbond, carded,wet-laid, meltblown, hydroentangled, or otherwise processed as is knownin the art. One suitable topsheet 24 comprising a web of staple lengthpolypropylene fibers is manufactured by Veratec, Inc., a Division ofInternational Paper Company, of Walpole, Mass. under the designationP-8.

Suitable formed film topsheets are described in U.S. Pat. No. 3,929,135,entitled “Absorptive Structures Having Tapered Capillaries”, whichissued to Thompson on Dec. 30, 1975; U.S. Pat. No. 4,324,246 entitled“Disposable Absorbent Article Having A Stain Resistant Topsheet”, whichissued to Mullane, et al. on Apr. 13, 1982; U.S. Pat. No. 4,342,314entitled “Resilient Plastic Web Exhibiting Fiber-Like Properties”, whichissued to Radel, et al. on Aug. 3, 1982; U.S. Pat. No. 4,463,045entitled “Macroscopically Expanded Three-Dimensional Plastic WebExhibiting Non-Glossy Visible Surface and Cloth-Like TactileImpression”, which issued to Ahr, et al. on Jul. 31, 1984; and U.S. Pat.No. 5,006,394 “Multilayer Polymeric Film” issued to Baird on Apr. 9,1991. Other suitable topsheets 30 are made in accordance with U.S. Pat.Nos. 4,609,518 and 4,629,643 which issued to Curro et al. on Sep. 2,1986 and Dec. 16, 1986, respectively, and both of which are incorporatedherein by reference. Such formed films are available from The Procter &Gamble Company of Cincinnati, Ohio as “DRI-WEAVE” and from TredegarCorporation of Terre Haute, Ind. as “CLIFF-T.”

The topsheet 24 may be made of a hydrophobic material or be treated tobe hydrophobic in order to isolate the wearer's skin from liquidscontained in the absorbent core 28. If the topsheet 24 is made of ahydrophobic material, preferably at least the upper surface of thetopsheet 24 is treated to be hydrophilic so that liquids will transferthrough the topsheet more rapidly. This diminishes the likelihood thatbody exudates will flow off the topsheet 24 rather than being drawnthrough the topsheet 24 and being absorbed by the absorbent core 28. Thetopsheet 24 can be rendered hydrophilic by treating it with a surfactantor by incorporating a surfactant into the topsheet. Suitable methods fortreating the topsheet 24 with a surfactant or incorporating a surfactantin a topsheet are described in U.S. Pat. No. 4,988,344 entitled“Absorbent Articles with Multiple Layer Absorbent Layers” issued toReising, et al. on Jan. 29, 1991 and U.S. Pat. No. 4,988,345 entitled“Absorbent Articles with Rapid Acquiring Absorbent Cores” issued toReising on Jan. 29, 1991, and U.S. Statutory Invention Registration No.H1670, published on Jul. 1, 1997 in the names of Aziz et al. Each ofthese references is hereby incorporated by reference herein.Alternatively, the topsheet 24 may include an apertured web or filmwhich is hydrophobic. This may be accomplished eliminating thehydrophilizing treatment step from the production process and/orapplying a hydrophobic treatment to the topsheet 24, such as apolytetrafluoroethylene compound like SCOTCHGUARD or a hydrophobiclotion composition, as described below. In such embodiments, it ispreferred that the apertures be large enough to allow the penetration ofaqueous fluids like urine without significant resistance.

Any portion of the topsheet 24 may be coated with a lotion as is knownin the art. Examples of suitable lotions include those described in U.S.Pat. No. 5,607,760 entitled “Disposable Absorbent Article Having ALotioned Topsheet Containing an Emollient and a Polyol PolyesterImmobilizing Agent” which issued to Roe on Mar. 4, 1997; U.S. Pat. No.5,609,587 entitled “Diaper Having A Lotion Topsheet Comprising A LiquidPolyol Polyester Emollient And An Immobilizing Agent” which issued toRoe on Mar. 11, 1997; U.S. Pat. No. 5,635,191 entitled “Diaper Having ALotioned Topsheet Containing A Polysiloxane Emollient” which issued toRoe et al. on Jun. 3, 1997; and U.S. Pat. No. 5,643,588 entitled “DiaperHaving A Lotioned Topsheet” which issued to Roe et al. on Jul. 1, 1997.The lotion may function alone or in combination with another agent asthe hydrophobizing treatment described above. The topsheet may alsoinclude or be treated with antibacterial agents, some examples of whichare disclosed in PCT Publication No. WO 95/24173 entitled “AbsorbentArticles Containing Antibacterial Agents in the Topsheet For OdorControl” which was published on Sep. 14, 1995 in the name of TheresaJohnson. Further, the topsheet 24, the backsheet 26 or any portion ofthe topsheet or backsheet may be embossed and/or matte finished toprovide a more cloth like appearance.

The topsheet 24 and backsheet 26 may be joined to each other, theabsorbent core 28 or any other element of the diaper 20 by anyattachment means known in the art. For example, the attachment means mayinclude a uniform continuous layer of adhesive, a patterned layer ofadhesive, or an array of separate lines, spirals or spots of adhesive.Alternatively, the attachment means may comprise heat bonds, pressurebonds, ultrasonic bonds, dynamic mechanical bonds, or any other suitableattachment means of combinations of these attachment means as are knownin the art.

The absorbent core 28 may comprise any absorbent material known in theart. The absorbent core 28 may be manufactured in a wide variety ofsizes and shapes (e.g., rectangular, hourglass, “T”-shaped, asymmetric,etc.) and may comprise a wide variety of liquid-absorbent materialscommonly used in disposable diapers and other absorbent articles such ascomminuted wood pulp, which is generally referred to as airfelt.Examples of other suitable absorbent materials include creped cellulosewadding; meltblown polymers, including coform; chemically stiffened,modified or cross-linked cellulosic fibers; tissue, including tissuewraps and tissue laminates; absorbent foams; absorbent sponges;superabsorbent polymers; absorbent gelling materials; or any other knownabsorbent material or combinations of materials.

The configuration and construction of the absorbent core 28 may also bevaried (e.g., the absorbent core(s) or other absorbent structure(s) mayhave varying caliper zones, a hydrophilic gradient, a superabsorbentgradient, or lower average density and lower average basis weightacquisition zones; or may comprise one or more layers or structures).However, the total absorbent capacity of the absorbent core 28 should becompatible with the design loading and the intended use of the diaper20.

Exemplary absorbent structures for use as the absorbent core aredescribed in U.S. Pat. No. 4,610,678 entitled “High-Density AbsorbentStructures” issued to Weisman et al. on Sep. 9, 1986; U.S. Pat. No.4,673,402 entitled “Absorbent Articles With Dual-Layered Cores” issuedto Weisman et al. on Jun. 16, 1987; U.S. Pat. No. 4,834,735, entitled“High Density Absorbent Members Having Lower Density and Lower BasisWeight Acquisition Zones”, issued to Alemany et al. on May 30, 1989;U.S. Pat. No. 4,888,231 entitled “Absorbent Core Having A Dusting Layer”issued to Angstadt on Dec. 19, 1989; U.S. Pat. No. 5,137,537 entitled“Absorbent Structure Containing Individualized, Polycarboxylic AcidCrosslinked Wood Pulp Cellulose Fibers” which issued to Herron et al. onAug. 11, 1992; U.S. Pat. No. 5,147,345 entitled “High EfficiencyAbsorbent Articles For Incontinence Management” issued to Young et al.on Sep. 15, 1992; U.S. Pat. No. 5,342,338 entitled “Disposable AbsorbentArticle For Low-Viscosity Fecal Material” issued to Roe on Aug. 30,1994; U.S. Pat. No. 5,260,345 entitled “Absorbent Foam Materials ForAqueous Body Fluids and Absorbent Articles Containing Such Materials”issued to DesMarais et al. on Nov. 9, 1993; U.S. Pat. No. 5,387,207entitled “Thin-Until-Wet Absorbent Foam Materials For Aqueous BodyFluids And Process For Making Same” issued to Dyer et al. on Feb. 7,1995; and U.S. Pat. No. 5,625,222 entitled “Absorbent Foam Materials ForAqueous Fluids Made From high Internal Phase Emulsions Having Very HighWater-To-Oil Ratios” issued to DesMarais et al. on Jul. 22, 1997. Eachof these patents is incorporated herein by reference.

The diaper 20 may also comprise one or more waist features 34 to helpprovide improved fit and containment. The elastic waist feature 34 maybe constructed in a number of different configurations including thosedescribed in U.S. Pat. No. 4,515,595 issued to Kievit et al. on May 7,1985; U.S. Pat. No. 4,710,189 issued to Lash on Dec. 1, 1987; U.S. Pat.No. 5,151,092 issued to Buell on Sep. 9, 1992; and U.S. Pat. No.5,221,274 issued to Buell on Jun. 22, 1993. Other suitable waistconfigurations may include waistcap features such as those described inU.S. Pat. No. 5,026,364 issued to Robertson on Jun. 25, 1991 and U.S.Pat. No. 4,816,025 issued to Foreman on Mar. 28, 1989. All of the abovementioned references are incorporated herein by reference.

The diaper 20 may also include a fastening system 40. The fasteningsystem 40 preferably maintains the first waist region 36 and the secondwaist region 38 in an overlapping configuration so as to provide lateraltensions about the circumference of the diaper 20 to hold the diaper 20on the wearer. The fastening system 40 preferably comprises tape tabsand/or hook and loop fastening components, although any other knownfastening means are generally acceptable. Some exemplary fasteningsystems are disclosed in U.S. Pat. No. 3,848,594 entitled “TapeFastening System for Disposable Diaper” issued to Buell on Nov. 19,1974; U.S. Pat. No. 4,662,875 entitled “Absorbent Article” issued toHirotsu et al. on May 5, 1987; U.S. Pat. No. 4,846,815 entitled“Disposable Diaper Having An Improved Fastening Device” issued toScripps on Jul. 11, 1989; U.S. Pat. No. 4,894,060 entitled “DisposableDiaper With Improved Hook Fastener Portion” issued to Nestegard on Jan.16, 1990; U.S. Pat. No. 4,946,527 entitled “Pressure-Sensitive AdhesiveFastener And Method of Making Same” issued to Battrell on Aug. 7, 1990;and the herein before referenced U.S. Pat. No. 5,151,092 issued to Buellon Sep. 9, 1992; and U.S. Pat. No. 5,221,274 issued to Buell on Jun. 22,1993. The fastening system may also provide a means for holding thearticle in a disposal configuration as disclosed in U.S. Pat. No.4,963,140 issued to Robertson et al. on Oct. 16, 1990. Each of thesepatents is incorporated herein by reference. Some exemplary hooks areavailable from Aplix under the trade names 960E and 960D. Exemplarysuitable loops are available from 3M under the trade name EBL and fromGuilford under the trade designation 18904. In alternative embodiments,opposing sides of the garment may be seamed or welded to form a pant soas to allow the article to be used as a pull-on type diaper, such as atraining pant.

The diaper 20 may also include side panels 30 constructed and joined tothe chassis in any suitable configuration. Examples of diapers withelasticized side panels are disclosed in U.S. Pat. No. 4,857,067,entitled “Disposable Diaper Having Shirred Ears” issued to Wood, et al.on Aug. 15, 1989; U.S. Pat. No. 4,381,781 issued to Sciaraffa, et al. onMay 3, 1983; U.S. Pat. No. 4,938,753 issued to Van Gompel, et al. onJul. 3, 1990; the herein before referenced U.S. Pat. No. 5,151,092issued to Buell on Sep. 9, 1992; and U.S. Pat. No. 5,221,274 issued toBuell on Jun. 22, 1993; U.S. Pat. No. 5,669,897 issued to LaVon, et al.on Sep. 23, 1997 entitled “Absorbent Articles Providing SustainedDynamic Fit”; EPO Publication No. WO 95/13775 A1, published May 26, 1995entitled “Absorbent Article With Multi-Directional Extensible SidePanels;” each of which is incorporated herein by reference.

The diaper 20 preferably further includes leg cuffs 32 to help provideimproved containment of liquids and other body exudates. Leg cuffs mayalso be referred to as leg bands, side flaps, barrier cuffs, or elasticcuffs. U.S. Pat. No. 3,860,003 describes a disposable diaper whichprovides a contractible leg opening having a side flap and one or moreelastic members to provide an elasticized leg cuff (a gasketing cuff).U.S. Pat. Nos. 4,808,178 and 4,909,803 issued to Aziz et al. on Feb. 28,1989 and Mar. 20, 1990, respectively, describe disposable diapers having“stand-up” elasticized flaps (barrier cuffs) which improve thecontainment of the leg regions. U.S. Pat. Nos. 4,695,278 and 4,795,454issued to Lawson on Sep. 22, 1987 and to Dragoo on Jan. 3, 1989,respectively, describe disposable diapers having dual cuffs, includinggasketing cuffs and barrier cuffs. In some embodiments, it may bedesirable to treat all or a portion of the leg cuffs with a lotion, asdescribed above.

Embodiments of the present invention may also include pockets forreceiving and containing waste, spacers which provide voids for waste,barriers for limiting the movement of waste in the article, compartmentsor voids which accept and contain waste materials deposited in thediaper, and the like, or any combinations thereof. Examples of pocketsand spacers for use in absorbent products are described in U.S. Pat. No.5,514,121 issued to Roe et al. on May 7, 1996, entitled “Diaper Havingis Expulsive Spacer”; U.S. Pat. No. 5,171,236 issued to Dreier et al onDec. 15, 1992, entitled “Disposable Absorbent Article Having CoreSpacers”; U.S. Pat. No. 5,397,318 issued to Dreier on Mar. 14, 1995,entitled “Absorbent Article Having A Pocket Cuff”; U.S. Pat. No.5,540,671 issued to Dreier on Jul. 30, 1996, entitled “Absorbent ArticleHaving A Pocket Cuff With An Apex”; and PCT Application WO 93/25172published Dec. 3, 1993, entitled “Spacers For Use In Hygienic AbsorbentArticles And Disposable Absorbent Articles Having Such Spacer”; and U.S.Pat. No. 5,306,266, entitled “Flexible Spacers For Use In DisposableAbsorbent Articles”, issued to Freeland on Apr. 26, 1994. Examples ofcompartments or voids are disclosed in U.S. Pat. No. 4,968,312, entitled“Disposable Fecal Compartmenting Diaper”, issued to Khan on Nov. 6,1990; U.S. Pat. No. 4,990,147, entitled “Absorbent Article With ElasticLiner For Waste Material Isolation”, issued to Freeland on Feb. 5, 1991;U.S. Pat. No. 5,062,840, entitled “Disposable Diapers”, issued to Holtet al on Nov. 5, 1991; and U.S. Pat. No. 5,269,755 entitled “TrisectionTopsheets For Disposable Absorbent Articles And Disposable AbsorbentArticles Having Such Trisection Topsheets”, issued to Freeland et al onDec. 14, 1993. Examples of suitable transverse barriers are described inU.S. Pat. No. 5,554,142 entitled “Absorbent Article Having MultipleEffective Height Transverse Partition” issued Sep. 10, 1996 in the nameof Dreier et al.; PCT Patent WO 94/14395 entitled “Absorbent ArticleHaving An Upstanding Transverse Partition” published Jul. 7, 1994 in thename of Freeland, et al.; and U.S. Pat. No. 5,653,703 entitled“Absorbent Article Having Angular Upstanding Transverse Partition”,issued Aug. 5, 1997 to Roe, et al. All of the above-cited references arehereby incorporated by reference herein.

Embodiments of the present invention may also include a waste managementdevice 110 such as is shown in FIG. 21. The waste management device 110may include a waste bag 111 to collect feces, urine or both. The wastebag 111 may have an aperture 121 and a flange 112 surrounding theaperture for preferably adhesive attachment to the perianal area of awearer. Further, the waste management device 110 has been found to beparticularly useful and beneficial when used in conjunction with agarment, or diaper, preferably a disposable diaper. One example of adiaper 120 including a waste bag 111 is shown in FIG. 22. If associatedwith a diaper 120 or other garment, the waste bag 111 may be disposed onor joined to any surface of the article. In one embodiment, the wastebag 111 is joined to the topsheet 124 of the diaper 120.

The waste bag 111 is preferably a flexible receptacle for thecontainment of excreted fecal matter or urine. Thus, the waste bag 111is preferably liquid impermeable, and yet it may be breathable. Further,the waste bag 111 is designed of sufficient strength to withstandtypical wearing conditions, such as sitting.

The waste bag 111 may comprise one or multiple layers. In oneembodiment, the waste bag 111 may comprise three layers, preferably onefilm and two non-woven layers. Suitable film materials for any of thefilm layers preferably comprise a thermoplastic material. Thethermoplastic material can be selected from among all types of hot-meltadhesives, polyolefins especially polyethylene, polypropylene, amorphouspolyolefins, and the like; material containing meltable componentscomprising fibres or polymeric binders including natural fibres such ascellulose—wood pulp, cotton, jute, hemp; synthetic fibres such asfibreglass, rayon, polyester, polyolefin, acrylic, polyamid, aramid,polytetrafluoroethylene metal, polyimide; binders such as bicomponenthigh melt/low melt polymer, copolymer polyester, polyvinyl chloride,polyvinyl acetate/chloride copolymer, copolymer polyamide, materialscomprising blends wherein some of the constituent materials are notmeltable; air and vapour permeable materials including microporous filmssuch as those described above with respect to the backsheet andmonolithic breathable materials such as HYTREL available from DuPont andPEBAX available from ELF Atochem, France.

The waste bag 111 may have any shape or size. Preferred shapes includeflat circular type bags, cone shaped bags, truncated cone shaped bagsand pyramidal or truncated pyramidal shaped bags and flat T shaped bags.Further, the waste bag 111 may be provided from a unitary piece ofmaterial or a number of separate pieces of material which may beidentical or different and which may be sealed at their respectiveperipheries.

The waste bag 111 may also contain absorbent material. The absorbentmaterial may comprise any absorbent material which is capable ofabsorbing and retaining liquids. The absorbent material may comprise awide variety of liquid-absorbent materials commonly used in disposablediapers and other absorbent articles. Some examples are described hereinwith respect to the absorbent core.

The waste bag 111 is provided with an aperture 121 whereby fecal matteror urine is received from the body prior to storage within the bagcavity. The aperture 121 is preferably surrounded by a flange 112 andmay be provided in any shape or size, such as circular, oblong, heartshaped and may be symmetrical or asymmetrical, preferably the aperturehas an oblong configuration either in the longitudinal or in thetransversal direction. The flange may comprise projections designed tofit the perineal, genital and/or coccygeal area of the wearer.

The flange 112 should be made of soft, flexible and malleable materialto allow easy placement of the flange 112 to the perianal or uro-genitalarea. Typical materials include nonwoven materials, wovens, open celledthermoplastic foams, closed-cell thermoplastic foams, composites of opencelled foams and stretch nonwoven, and films.

The waste bag 111 preferably further comprises means for joining thedevice to the wearer. Such means may comprise any of thejoining/attachment mechanisms described herein or known in the art, andmay include for example straps, belts, ties, tapes, hooks (or hook andloop) structures, and/or a body-compatible pressure sensitive adhesiveapplied to the wearer facing portion of the waste bag 111 or the flange.Any skin-friendly water resistant pressure sensitive adhesive may beused to join the device to the perianal or uro-genital area of thewearer, such as hydrocolloid adhesives and hydrogel adhesives.Particularly effective adhesives in providing the desired adhesiveproperties to secure the flange to the skin of the wearer at thesensitive perianal area, while allowing for relatively painlessapplication and removal, are formed from crosslinking polymers with aplasticizer to form a 3-dimensional matrix.

The article of the present invention may also include one or more fecesmodifying agents (“FMAs”, “viscous bodily waste modifying agents”,“modifying agents” or “agents”) in an effective concentration capable ofmodifying the chemical or physical properties (e.g., adhesiveness) ofviscous bodily waste, such as feces and menses. As used herein, “fecesmodifying agent” (or FMA) refers to any chemical composition capable ofincreasing the hardness of a given fecal analog, or preferably actualfeces, by at least about 100% or decreasing the hardness of a givenfecal analog, or preferably actual feces, by at least about 25%, asmeasured by the Hardness Method, described below. However, depending onthe particular article design and the type of feces, embodiments arecontemplated which increase or decrease the effective viscosity offeces, increase or decrease the ease of dewatering the feces, decreasethe stickiness of the feces, decrease the adhesion characteristics ofthe feces, or any combination of the above. Although the feces modifyingagents of the present inventions may be capable of modifying theproperties of solid feces, the FMAs are generally most effective inaltering the properties of viscous fluid feces which generally have aviscosity of greater than about 10 cP and less than about 10⁷ cP at ashear rate of one 1/sec, (at about 35 degrees C.), and more particularlybetween about 10² cP and 10⁷ cP at a one 1/sec shear rate, in acontrolled stress rheometry test using parallel plates on a controlledstress rheometer. (For reference, water is at 1.0 cP at 20 degrees C.and Jif Creamy peanut butter (available from the Procter & Gamble Co.,Cinti., OH) is approximately 4×10⁵ cP at 25 degrees C. at this sameshear rate). The method for determining viscosity, as used herein, isdescribed in detail in the Test Methods section below.

Regardless of the specific effect of the chemical agent on feces, theagent must be available to the feces in order to perform its function.As used herein, in the context of FMAs, or other compositions forenhancing feces removability, the term “available” indicates that thecomposition/agent is positioned within the article or presented by thearticle or a component of the article during the course of normalwearing of the article so as to directly contact at least a portion ofthe feces deposited in the article or on the wearer's skin, or so as tocontact at least a portion of the wearer's skin so that the agent orcomposition can be transferred to at least a portion of the feces. Ifthe composition/agent is positioned within a structure (e.g., in anabsorbent layer under a topsheet) the structure must be substantiallypenetrable by the feces. In such cases, the agent is “available” if thestructure has an Acceptance Under Pressure greater than about 0.50g/cm2/J, and preferably greater than about 1.0 g/cm2/J, as measured bythe Acceptance measurement described in the Methods section below. Ifthe agent is encapsulated, it should be released by the article at orabout the time when the feces insults the article. For example, the FMAmay be retained by a water-soluble film which, upon contact with urineor fecal water, dissolves and releases the FMA to contact the fecesand/or skin.

An “effective concentration” of an FMA, as used herein, refers to therelative amount of the agent required to have a measurable effect on theHardness (as measured by the Hardness Method described below) of atleast a portion of the feces in the article or on the skin of thewearer. Data illustrating an “effective concentration” is providedbelow. Preferably, a concentration of an FMA of at least about 0.01weight percent of the feces to be treated is desirable, and moretypically between about 0.1 and about 50 weight percent of the FMA isavailable to the feces. For example, to treat an entire 25 gram fecesloading in a diaper (i.e., a “bulk” treatment) at a 5 weight percentlevel, 1.25 grams of the FMA must be available to the fecal mass(assuming the specific gravity of the feces is 1.0). Thus, the FMA ispreferably present in the article in concentrations ranging from about0.001% to about 50% by weight of the article. Typically, however, theconcentration is between about 0.01 and about 20 weight percent of thearticle.

The FMA is preferably capable of reducing the Hardness of a fecalanalog, and preferably, actual feces, by about 25% or increasing theHardness by about 100% at a concentration of no more than about 20weight percent of the feces to be treated at room temperature (20-25°C.). More preferably, the FMA is capable of reducing the Hardness of afecal analog or actual feces by about 25%, or increasing the Hardness byabout 100% at a concentration of no more than about 10 weight percent ofthe feces to be treated. Even more preferably, the FMA is capable ofreducing the Hardness of a fecal analog or actual feces by about 25%, orincreasing the Hardness by about 100% at a concentration of no more thanabout 5 weight percent of the feces to be treated. In other preferredembodiments, the FMA is capable of reducing the Hardness of a fecalanalog or actual feces by 25%, or increasing the Hardness by about 100%at a concentration of no more than about 1 weight percent of the fecesto be treated. In yet other preferred embodiments, the FMA is capable ofreducing the Hardness of a fecal analog or actual feces by about 25%, orincreasing the Hardness by about 100% at a concentration of no more thanabout 0.5 weight percent of the feces to be treated. Typically, the FMAis capable of reducing the Hardness of a fecal analog or actual feces byabout 25%, or increasing the Hardness by about 100% at a concentrationof between about 0.1 and about 10 weight percent of the feces to betreated.

Preferably, the defined reduction or increase in Hardness is effectedwithin the range of within about 30 minutes, more preferably withinabout 15 minutes, even more preferably within about 5 minutes, even morepreferably within about 3 minutes, and most preferably in about 1 minuteafter contact with the feces. Typically, the desired Hardness change iseffected within the range of about 1 minute to about 10 minutes. In morepreferred embodiments, the defined reduction or increase in Hardness iseffected within about 3 minutes at an FMA concentration of no more thanabout 5% by weight of the feces to be treated or within 3 minutes at anFMA concentration of about 1.5% by weight of the feces to be treated. Inother preferred embodiments, the FMA is capable of increasing theHardness of a fecal analog, or actual feces, by about 200% within about3 minutes at a concentration of no more than about 5%. In yet otherpreferred embodiments, the FMA is capable of increasing the Hardness ofa fecal analog, or actual feces, by about 400% within about 3 minutes ata concentration of no more than about 5%.

In other preferred embodiments, the FMA is capable of reducing theHardness of a fecal analog, or actual feces, by about 50% within about 3minutes at a concentration of no more than about 5%.

The reference Hardness values of two synthetic fecal analog materialsare presented in Table I. (Hardness has been found to be closely relatedto the complex modulus of feces.) Analog A represents the water content,Hardness, and adhesion properties of typical “runny” feces, while AnalogB represents typical “pasty” feces. Two consistencies of feces aresimulated so as to better illustrate the activity of the FMAs. Themethods of preparing Analogs A and B are described in the Test Methodssection below.

TABLE I Fecal Analog Fecal Analog Hardness (g) A 8.6 B 620

Fecal analogs A and B provide a robust and repeatable means to evaluateFMA performance. However, actual feces is a very complex material. Forcertain chemical treatments, the FMA effect may be greater for actualfeces than for either of the analogs described above. For one of theagents evaluated, Hardness data is presented in terms of hardness changefor feces analogs and actual feces, in order to demonstrate thesimilarity in relative responses to the treatment. The actual feces usedin these experiments consisted of both a composite “runny” feces sampleand a composite “pasty” feces sample. The composite runny feces samplewas pooled using several bowel movements (uncontaminated by urine)produced by two U.S. breast-fed, four month old, male infants. Thecomposite “pasty” sample was pooled using several bowel movements(uncontaminated by urine) produced by two U.S. infants—a four month old,formula-fed male and a 12 month old male eating a “transition” dietbetween breast milk and table food. Feces pooling was accomplished via aSeward Stomacher 400 Lab System by Seward Medical, Ltd. of London, UK.For reference, the Hardness of the untreated (i.e., as collected) pooledrunny feces sample was 28 grams, and the Hardness of the untreatedpooled pasty feces sample was 297 grams.

The effect of mixing several comparative examples with fecal analogs areillustrated in Table II below. All comparative materials were mixed withthe fecal analog as described below in the Sample Preparation Method. Asis evident in the data above, the desired changes in Hardness were notachieved by the comparative materials.

TABLE II Treated Fecal Concentration Fecal Analog Analog ComparativeAdditive (wt.%) Hardness (g) A Corn Starch 1.0 12.6 (Dietary FiberControl, 5.0 8.6 Sigma Chemical Co., St. Louis, MO, S-2388) A Pure CornStarch Baby 1.0 14.4 Powder (Johnson & 5.0 7.1 Johnson, Co., Skillman,NJ) A Baby Powder (talc) 1.15 10.2 (Johnson & Johnson, Co.) B CornStarch 1.1 643 (Dietary Fiber Control, 4.9 533 Sigma Chemical Co., St.Louis, MO, S-2388) B Baby Powder (talc) 1.0 854 (Johnson & Johnson, Co.)5.0 679

The Feces Modifying Agent of the present invention may include one ormore “water liberating” agents capable of separating the liquid portionof the feces (i.e., water) from the solid structure of the feces and/orreducing the degree of “binding” of the feces water to the solid fecescomponents. Without wishing to be bound by theory, it is believed thatfeces comprises water in several states. For example, the feces includesfree water, bound water (bound water may be held in a “colloidal”structure via an electrical double layer on the surface of theparticles, organized in a polymeric “gel” structure, or associated withother charged elements in the fecal matrix), and entrapped water (e.g.,inside bacteria). It is also believed that the solid and polymericcomponents of the feces act to organize bound water into higher energystates (i.e., more energy is required to separate the water from thematrix) as compared to free water or “unbound” water. (The solidcomponents of feces (soluble and insoluble) generally include one ormore of the following; undigested food material (e.g., fiber), bacteria,long chain polysaccharides, fats, soaps, protein globules, and thelike.) The water content of viscous bodily wastes such as fecal materialis relatively high, generally greater than 50%, and often between about60% and about 95% by weight. However, conventional absorbent articlesare incapable of separating much of the water from the fecal matrix. (Asused herein, the term “fecal matrix” refers to the feces as a whole,including any solid or soluble components such as bio polymers.) Thus,very little of the feces (generally only a portion of the free water) isactually absorbed such that it can be adequately contained.

Including “water liberating” agents, which act to separate the boundand/or entrapped water from the fecal matrix, in the FMAs or othercompositions of the present invention may improve the efficacy of theabsorbent structure with regard to feces, and/or the removability offeces from the wearer's skin. “Liberated water” in feces or analogs mayremain within the feces mass resulting in reduced feces viscosity, orcompletely separate from feces forming two distinct phases, water andthe remaining feces. If the water is completely separated, the remainingfeces becomes significantly harder and less adhesive. In the absence ofabsorbent materials in contact with the feces, liberation of water fromthe fecal matrix decreases the viscosity of the overall fecal mass bypermitting the liquid portion of the fecal matter to flow more freely.If, however, the liberated water is completely separated from the fecalmass, the viscosity or hardness of the remaining feces will beincreased. Further, the removal of water helps to agglomerate the fecalsolids into more discrete solid particles which are generally morestrongly associated with each other than when held in the matrix (it isbelieved that a reduction in inter-particle repulsive forces causes theparticles to aggregate and release water held between them). The feces'decrease in viscosity generally reduces its adhesion to the skin andpromotes its penetration into the absorbent structure. Accordingly, theabsorbent article's overall performance may be significantly improved.

While the liberation of water caused by the destabilization of thecolloidal or gel nature of the feces preferably decreases the viscosityand adhesion of the feces and increases the ability of the feces to flowinto the absorbent structure, it may also enhance the ability of anyabsorbent materials in contact with the treated feces to dewater andimmobilize the feces. However, in some embodiments it may be undesirableto have immobilization occur on the surface of the absorbent structurebecause the solid fraction of the feces may still be accessible to theuser. Thus, it maybe preferred to limit the contact of viscous bodilywaste with absorbent media until the feces has penetrated the structureto the desired depth or location for immobilization away from the user.In such embodiments, the feces viscosity is preferably decreased whileon the surface of, or prior to contact with the absorbent structure, anddewatered and/or immobilized once it has sufficiently penetrated thestructure.

Feces Modifying Agents which act to decrease the viscosity of feces asdescribed above include, but are not limited to the following: organicand inorganic flocculants, and the like. Inorganic flocculants includebut are not limited to divalent and trivalent metal salts, including butnot limited to salts of iron, aluminum, calcium, and sodium and mixturesthereof. It is believed that such salts form hydrolysis products whichassociate with the charged surfaces of the particulate matter in thefeces colloidal structure, resulting in flocculation (i.e., flocculationvia any of the mechanisms described above). Some examples includeferrous chloride, ferric chloride, aluminum sulfate, aluminum chloridehydroxide, sodium aluminate, calcium sulfate,poly-aluminum-silicate-sulfate (available from Handy Chemical, Quebecunder the trade name PASS), ferrous sulfate, calcium carbonate, and thelike.

Organic flocculants include but are not limited to natural substanceslike albumin, xanthan gum, and guar gum. Synthetic flocculants aregenerally non-crosslinked, water-soluble molecules or polymers and mayinclude acrylic and acrylamide polymers and their derivatives (in verylow concentrations (a few hundredths of a weight percent)), polyvinylpyrollidone, poly methacrylates, polyamines, polyethylene oxide, andallylamine polymers. Preferably, these are cationic polymeric species.(Although applicants do not wish to be bound by theory, it is believedthat these agents function by associating with the negatively chargedregions of the feces particulate fraction and reducing the netinter-particle repulsive charge.) Some of the synthetic flocculants mayact to increase the viscosity of aqueous solutions if used in highconcentrations and will be discussed below as feces thickening agents.It is also important to note that if some of the organic flocculants areused in too high a concentration their effect may be reversed. Thus, thewater may be held more tightly by the feces due to the tendency of theseagents to form gels if used in excess of the amount necessary toassociate with the charged particulates.

Without wishing to be bound by theory, it is believed that flocculantsdestabilize colloids by enhancing aggregation of the constituentparticles in the matrix via any of a number of mechanisms, includingcharge neutralization, bridging, and electrostatic patching.Flocculation of colloidal systems via charge neutralization occurs whenthe agent adsorbs to the surface of the constituent particles andreduces the electrical double-layer potential. The agent acts in theory,to reduce the stabilizing repulsive surface charges at the surface ofthe solid particles in the matrix by accumulating at the chargedinterfaces of the particles, allowing the particles to aggregate. Thus,the water that was held “bound” in the matrix (i.e., held between theparticles) is freed as the structure collapses. It is believed that“bridging” may occur when a long-chain polyelectrolyte adsorbs ontoparticles in the colloidal matrix and extends into the bulk of thematrix, where it can span the distance of closest approach of otherparticles in the matrix. This results in the aggregation of particlesand the freeing of bound water. “Electrostatic patching” may occurwhere, as the flocculating polymer is completely adsorbed onto theparticle, geometric limitations prevent complete charge neutralization.This may result in the formation of positive “patches” or areas on theparticles that attach to negative patches on other particles uponcollision. This also results in aggregation of the particles due to thenet reduction in electrical repulsion between the particles.

Some crosslinked derivatives of the synthetic organic flocculants (e.g.,polyacrylates), or derivatives thereof, are known in the art assuperabsorbent polymers, and function to form water-insoluble gels uponcontact with very low viscosity aqueous wastes such as urine and menses.However, because these crosslinked species cannot readily dissociate(i.e., dissolve) and adsorb to the particulate species within the fecesmatrix, they do not function as flocculants.

Viscosity reduction performance of several representativewater-liberating agents is illustrated in the data in Table III. Themixing of the agent and the fecal analog or feces is described below inthe Sample Preparation Method).

TABLE III Treated Fecal % Analog Change Fecal Concentration Hardness inAnalog Flocculant (wt. %) (g) Hardness A calcium hydroxide 1.1 5.7  (34) * (ACS Reagent, Sigma Chemical Co., St. Louis, MO C-5551) Acalcium sulfate 1.0 4.9 (43) hemihydrate (#30, 766-1 Aldrich ChemicalCo., Milwaukee, WI) B polyvinyl pyrollidone 1.0 425 (31) (PVP) (Avg. MW= 40,000, k-value: 29-32, Sigma PVP-40) B sodium 2.4 446 (28)polymethacrylate (30 wt % solution in water, Avg. MW = 6000, Avg. Mn =4000, Aldrich #43, 449-3) B sodium 4.7 411 (34) polymethacrylate * ( )indicates decrease in the value.

Feces Modifying Agents which act to decrease the viscosity and/oradhesion of feces as described above may also include reducing agents.For example, agents that reduce disulfide bonds (—S—S-bonds) as found incolonic mucous colomin mucous generally comprises (macromolecularglycoproteins linked by disulfide bonds) can effect a significantviscosity reduction in feces having high mucous content. While notwishing to be bound by theory, it is believed that reduction of themucin disulfide bonds (which function as crosslinks between mucinpolymer chains) significantly reduces the average molecular weight ofthe glycoprotein structure in feces such as runny feces to a level wellbelow the “gel point” of the mucin (i.e., long-distance structurebecomes impossible due to the relatively small size of theglycoproteins). Exemplary reducing agents include sulfites such assodium hydrogensulphite, sodium sulfite and sodium dithionite, thiolsand thiol alcohols (e.g., 2-mercaptoethanol, dithiothreitol, anddithioerythritol), mercaptoacetic acid, sodium thioglycolate, thiolacticacid, thioglycolamide, glycerol monothioglycolate, borohydrides (e.g.,sodium borohydride), tertiary amines, thiocyanates such as sodiumthiocyanate, thiosulfates such as sodium thiosulfate, thiophosphatessuch as sodium thiophosphate, arsenites such as sodium arsenite,phosphines such as triphenyl phosphine, phenols such as thiophenol andp-nitrophenol, betaines, and others including, but not limited to,lithium aluminumhydride, aluminum chloride, guanidine hydrochloride,stannous chloride, hydroxylamine, and LiHB(C₂H₅)₃.

Viscosity reduction performance of a representative reducing agent(mixed with a fecal analog and actual feces as described in the SamplePreparation Method in the Test Methods section below) is illustrated inthe data in Table IV.

TABLE IV Treated Feces/Fecal % Change Feces/Fecal Concentration Analogin Analog Reducing Agent (wt. %) Hardness (g) Hardness Composite sodium5.0 10.1   (50) * Runny Feces hydrogensulfite Sample (Aldrich. #24,397-3) B sodium 5.0 311 (64) hydrogensulfite (see above) * ( ) indicatesdecrease in the value.

In other particularly preferred embodiments of the present invention,modifying agents which generally increase the structure of the feces byincreasing the degree of water binding are employed to increase theviscosity and reduce the adhesion and mobility of the feces. This may beaccomplished via the use of thickening agents in the appropriateconcentrations. Thickening agents may be natural or synthetic and aregenerally water-soluble, (typically non-crosslinked) polymers, such asCMC (carboxymethyl cellulose), hydroxypropyl methylcellulose,hydroxyethyl cellulose, polyacrylic acid and its derivatives,carageenan, polyacrylamide and its derivatives, (polyethylene)imines,gums (such as xanthan, guar, karaya, agar, locust bean gum, pectin, andgum ghatti, or mixtures thereof) and other similar materials. Cationicpolymers are preferred due to the anionic surfaces of fecal bacteria andbiopolymers. Thickening agents increase the viscosity of the feces bydissolving in the free water in the feces and osmotically “binding”water, thereby increasing the solid “structure” of the feces. Generally,large, insoluble polyelectrolytic polymeric particles such asconventional superabsorbents are not able to dissolve in the feces freewater and create a matrix within the feces at the molecular level. SomeFMAs may perform differently on different types of feces (e.g., a FMAthat acts as a flocculant on one type of feces, may act as a thickeningagent on another type due to variance in the structural character of thespecific type of feces). One example of this is calcium hydroxide whichfunctions as a flocculant for a runny fecal analog, but as a thickenerfor a pasty fecal analog in the same concentrations.

Table V shows the effects of concentration of various FMAs acting asthickening agents on the fecal analogs and/or feces. The mixing of theagent and the fecal analog or feces is described below in the SamplePreparation Method.

TABLE V Treated Feces/Fecal Feces/Fecal Concentration Analog AnalogThickener (wt. %) Hardness (g) A Gum Guar 1.1 35 (Sigma G-4129) 5.0 110A poly(acrylamide 1.2 9.6 co-acrylic acid) 4.9 101 (Avg. mw = ca. 5 ×10⁶, Aldrich #18, 127-7) A poly acrylamide 1.0 130 (ground into powder,5.0 536 Sigma P-2433) B carboxymethyl 2.5 55 cellulose (CMC) 5.0 36810.0 935 B Gum Xanthan 2.5 56 (practical grade, 10.0 362 Sigma G-1253) Bcarageenan 5.0 1641 (Type I, commercial grade, Sigma C-10 13) compositecarageenan 5.0 150 runny feces (see above) sample B hydroxypropyl 5.01775 methylcellulose (Sigma H-7509) composite hydroxypropyl 5.0 111runny feces methylcellulose sample (see above) composite pastyhydroxypropyl 5.0 1060 feces sample methylcellulose (see above)

In still other preferred embodiments, the modifying agent comprises anionic complexing agent. Ionic complexing agents may include any singlecomponent which complexes with itself or water or other chemicalentities in the feces to form regions of increased structure andrigidity within the feces. The resultant complex acts to stabilize orbind water more tightly in the feces. Exemplary ionic complexing agentsinclude ZnO, MgO, MnO, CaO, calcium hydroxide, Al₂O₃, aluminum salts,zinc salts such as zinc acetate and zinc gluconate, gelatin, quaternaryammonium salts, ethanolamines, alginic acid, cetyl trimethyl ammoniumbromide and the like). Alternatively, the ionic complexing agent maycomprise a two (or more) component system, wherein the complex (i.e.,longer-range structure) is created by the interaction of the two addedcomponents (e.g., aluminum, calcium, or zinc salts plus alginic acidand/or salts thereof). The ionic complexing agents may form crystalhydrates when complexing with water. In general, calcium-containingcompounds or systems (e.g., CaO, calcium hydroxide, and calciumalginate, etc.) are some of the most effective feces modifying agents.

Table VI shows the effect of various ionic complexing agents on fecalanalog or feces Hardness. (Mixing of the fecal analog and/or feces wasperformed as specified in the Sample Preparation Method below.)

TABLE VI Treated Fecal Fecal Ionic Complexing Concentration Analog/FecesAnalog/Feces Agent/System (wt. %) Hardness (g) A calcium oxide 1.0 26(Sigma C-2178) 5.0 385 A alginic acid/zinc chloride 5.0 114 (50%/50% bywt.) (total mixture) (alginic acid - sodium salt, from kelp, “highviscosity”-Sigma A-7128; zinc chloride- Sigma Z-4875) B calciumhydroxide 1.0 1206 (ACS reagent, 5.0 1223 Sigma C-5551) B zinc oxide 5.11192 (ACS reagent, Sigma Z-1753) B sodium chloride 5.2 1275 (ACSReagent, Sigma S-9888) B calcium chloride 4.9 1405 (anhydrous, SigmaC-4901) A alginic acid, 5.0 513 ammonium-calcium salt (Sigma A-7253) Balginic acid, 5.0 2070 ammonium-calcium salt (Sigma A-7253) Compositealginic acid, 5.0 52 runny feces ammomum-calcium salt (Sigma A-7253)Composite alginic acid, 5.0 908 pasty feces ammonium-calcium salt (SigmaA-7253)

In still other preferred embodiments, the FMA includes a crosslinkerthat can react with functional groups on the components of the feces orwith itself to form long distance structure in the fecal matrix. Thecrosslinking effect uses the fecal components as “monomers” that arelinked together by a multifunctional (e.g., difunctional) modifyingagent to form a longer-range network structure. Such modifying agentsmay target amine groups (e.g., dialdehydes, dialdehyde starches),hydroxl groups (e.g., epichlorohydrin), and/or carboxyl groups (e.g.,diamines). Other exemplary FMA crosslinking agents are Kymene 557-H,557-LX, and 2064 (available from Hercules, Inc. of Wilmington, Del.).Table VII shows the effects of an exemplary crosslinking agents on fecalanalog Hardness after 15 minutes (t=15 minutes after beginning thestirring process, as described in the Sample Preparation Method below).

TABLE VII Fecal Analog Analog Crosslinking Agent Concentration (%)Hardness B Kymene 2064 5.0 1405 (Hercules, Inc., Wilmington, DE)

While in certain embodiments it is desirable to treat the entire mass offeces within the article (i.e., “bulk” treatment), in some preferredembodiments only a portion of the feces is treated with the FMA. Inthese embodiments the FMA may penetrate only a relatively small distanceinto the feces, thereby forming a modified external layer that isrelatively stiff and non-sticky (i.e., significantly less adhesive).This may be preferable from an FMA utilization standpoint or toeliminate the need for mixing of the FMA into the fecal mass. Themodified external layer is a region or layer of feces at or near thesurface of the feces mass with different physical properties than theremainder of the feces mass. Preferably, the modified layer is harder(i.e., has a higher yield stress), less sticky, and/or has a higherresistance to diffusion of volatile molecules contained in the fecesthan does the remaining feces, resulting in decreased spreading/mobilityof the feces mass and/or decreased adhesion of the feces mass to thewearer's skin and/or reduced fecal odor. Preferably, the modifiedexternal layer region is between about 1 and about 1000 microns inthickness and may cover all or any portion of the fecal mass. Forexample, it may be suitable to treat only the feces at the skin/fecesinterface (e.g., to reduce adhesion and/or promote cleaning or reducespreading across the wearer's skin or to promote absorption or to reducespreading within the article). Thus, to treat a 1 millimeter thick layerof a fecal mass over a 30 square cm area of the skin or article topsheetat a 10 weight percent level, 0.30 grams of the FMA must be available tothe feces in the region of contact with the feces (assuming the specificgravity of the feces is 1.0).

In various embodiments, the FMA may be organic or inorganic, a lowmolecular weight molecule or polymeric in nature, and/or may be aliquid, solid (e.g., powder, fiber, film, web), or a semi-solid, orcombinations thereof. The FMA may include, or be combined with, anyanti-adherent as known in the art, such as TEFLON microparticles. TheFMA may be presented in a water/oil or oil/water emulsion, a suspension,or mixture. The FMA may be disposed in the article as an individualdiscrete element (e.g., as a fibrous batt or layer within or attached tothe article) or may be associated with (e.g., at least temporarily heldin or on) a carrier vehicle, such as a lotion or skin care composition(described below), a web, a film, a fibrous structure such as a brush, aloop structure such as used for a loop fastening component as describedabove, or in a packet, cell or envelope which releasably encapsulatesthe FMA.

In embodiments wherein the FMA is delivered to the feces and/or skin viaa skin care composition, it may be soluble in the skin care compositionor may be held in suspension or as a simple mixture. Larger FMAparticles (e.g., preferably greater than about 250 microns in largestdimension) may be at least partially embedded in or held adhesively bythe skin care composition. Some exemplary materials useful in the skincare compositions which may be used in embodiments of the presentinvention include Category I actives as defined by the U.S. Federal Foodand Drug Administration's (FDA) Tentative Final Monograph on SkinProtectant Drug Products for Over-the-Counter Human Use, which presentlyinclude: alantoin, aluminum hydroxide gel, calamine, cocoa butter,dimethicone, cod liver oil (in combination), glycerine, kaolin,petrolatum, lanolin, mineral oil, shark liver oil, white petrolatum,talc, topical starch, zinc acetate, zinc carbonate, zinc oxide, and thelike. Other potentially useful materials are Category III actives asdefined by the U.S. Federal Food and Drug Administration's TentativeFinal Monograph on Skin Protectant Drug Products for Over-the-CounterHuman Use tentative final monograph on skin protectant drug products forover-the-counter human use, which presently include: live yeast cellderivatives, aldioxa, aluminum acetate, microporous cellulose,cholecalciferol, colloidal oatmeal, cysteine hydrochloride,dexpanthanol, Peruvian balsam oil, protein hydrolysates, racemethionine,sodium bicarbonate, Vitamin A, and the like. Many of the FDA monographedskin care ingredients are currently utilized in commercially availableskin care products, such as A and D® Ointment, VASELINE® PetroleumJelly, DESITIN® Diaper Rash Ointment and Daily Care Ointment, GOLD BOND®Medicated Baby Powder, AQUAPHOR® Healing Ointment, BABY MAGIC® BabyLotion, JOHNSON'S ULTRA SENSITIVE® Baby Cream, Johnson's baby lotion,lip balms, etc. Other suitable skin care compositions are described indetail in U.S. Pat. No. 5,643,588, U.S. Pat. No. 5,607,760, U.S. Pat.No. 5,609,587, and U.S. Pat. No. 5,635,191. The disclosures of each ofthese patents is incorporated herein by reference.

The skin care compositions useful in the present invention preferablyhave a melting profile such that they are relatively immobile andlocalized on the wearer-contacting surface of the article at roomtemperature, are readily transferable to the wearer at body temperature,and yet are not completely liquid under extreme storage conditions.Preferably, the compositions are easily transferable to the skin by wayof normal contact, wearer motion, and/or body heat.

In preferred embodiments, the skin care compositions useful herein aresolid, or more often semi-solid, at 20° C., i.e. at ambienttemperatures. By “semisolid” is meant that the composition has arheology typical of pseudoplastic or plastic liquids. When no shear isapplied, the compositions can have the appearance of a semi-solid butcan be made to flow as the shear rate is increased. This is due to thefact that, while the compositions may contain primarily solidcomponents, they may also include some minor liquid components.Preferably, the compositions of the present invention have a zero shearviscosity between about 1.0×10⁶ centipoise and about 1.0×10⁸ centipose.More preferably, the zero shear viscosity is between about 5.0×10⁶centipoise and about 5.0×10⁷ centipoise. As used herein the term “zeroshear viscosity” refers to a viscosity measured at very low shear rates(e.g., 1/sec) using plate and cone viscometer (a suitable instrument isavailable from TA Instruments of New Castle, Del. as model number CSL100). One of skill in the art would recognize that using means otherthan high melting point components can be used to provide comparableviscosities. For example, the lotion could be provided with a structurewhich has a high zero shear viscosity but, on the application of shear,such structure collapses with a resulting viscosity reduction(Compositions of this type are said to have a yield value.) Suchstructure can be provided by certain clay materials, such as bentoniteclays or montmorillonite clays, and by fumed silica. Particularlypreferred are the fumed silicas as are available from the Cabot Corp.,Cab-O-Sil Div. Of Tuscola, Ill. as CAB-O-SIL. A skilled person wouldalso recognize that the zero shear viscosity of such compositions may bemeasured by extrapolating a plot of viscosity vs. shear rate to a shearrate of zero. Such viscosity measurements should be conducted at atemperature of about 20° C.

The skin care composition carrier vehicle may include a useful activeingredient such as one or more skin protectants or emollients. As usedherein, the term “emollient” refers to a material that protects againstwetness or irritation, softens, soothes, supples, coats, lubricates,moisturizes, protects and/or cleanses the skin. (It will be recognizedthat several of the monographed actives listed above are “emollients”,as that term is used herein.) In a preferred embodiment, emollients willhave either a plastic or liquid consistency at ambient temperatures,i.e., about 20° C. Such a consistency allows the composition to impart asoft, lubricious, lotion-like feel.

Representative emollients useful in the present invention include, butare not limited to, emollients that are petroleum-based, such aspetroleum oils and/or waxes; sucrose ester fatty acids; polyethyleneglycol and derivatives thereof; humectants; fatty acid ester type; alkylethoxylate type; fatty acid ester ethoxylates; fatty alcohol type;polysiloxane type, such as silicone oils and/or waxes; propylene glycoland derivatives thereof; glycerine and derivatives thereof, includingglyceride, acetoglycerides, and ethoxylated glycerides of C₁₂-C₂₈ fattyacids; triethylene glycol and derivatives thereof, spermaceti or otherwaxes; fatty acids; fatty alcohol ethers, particularly those having from12 to 28 carbon atoms in their fatty chain, such as stearic acid;propoxylated fatty alcohols; other fatty esters of polyhydroxy alcohols;lanolin and its derivatives; kaolin and its derivatives; any of themonographed skin care agents listed above; or mixtures of theseemollients.

Another preferred component of the skin care composition carriervehicles useful in the present invention is an agent capable ofimmobilizing the composition (including the preferred emollient and/orother skin conditioning, therapeutic or protective agents and/or theFMA(s) present in the composition) in the desired location in or on thetreated article. The immobilizing agent may counteract the tendency ofan emollient to migrate or flow by keeping the emollient primarilylocalized on the surface or in the region of the article to which thecomposition is applied. This is believed to be due, in part, to the factthat the immobilizing agent raises the melting point and/or viscosity ofthe composition above that of the emollient. Since the immobilizingagent is preferably miscible with the emollient (or solubilized in theemollient with the aid of an appropriate emulsifier or dispersedtherein), it entraps the emollient on the surface of the article'swearer contacting surface or in the region to which it is applied.

It is also advantageous to “lock” the immobilizing agent on the wearercontacting surface or the region of the article to which it is applied.This can be accomplished by using immobilizing agents which quickly setup (i.e., solidify) upon application to the article. In addition,outside cooling of the treated article via blowers, fans, cold rolls,etc. can speed up crystallization of the immobilizing agent.

In addition to being miscible with (or solubilized in) the emollient,the immobilizing agent preferably has a melting profile that provides acomposition that is solid or semisolid at ambient temperature. In thisregard, preferred immobilizing agents have a melting point of at leastabout 35° C. This prevents the immobilizing agent from having a tendencyto migrate or flow. Preferred immobilizing agents will have meltingpoints of at least about 40° C., and more typically in the range of fromabout 50° to about 150° C.

Immobilizing agents suitable for use in the present invention can beselected from any of a number of agents, so long as the preferredproperties of the skin care composition provide the skin benefitsdescribed herein. Preferred immobilizing agents generally comprise amember selected from the group consisting of C₁₄-C₂₂ fatty alcohols,C₁₂-C₂₂ fatty acids, and C₁₂-C₂₂ fatty alcohol ethoxylates having anaverage degree of ethoxylation ranging from 2 to about 30, and mixturesthereof. Preferred immobilizing agents include C₁₆-C₁₈ fatty alcohols,preferably crystalline high melting materials selected from the groupconsisting of cetyl alcohol, stearyl alcohol, behenyl alcohol, andmixtures thereof. (The linear structure of these materials can speed upsolidification on the treated absorbent article.) Other preferredimmobilizing agents include C₁₆-C₁₈ fatty acids, preferably selectedfrom the group consisting of palmitic acid, stearic acid, and mixturesthereof. Still other preferred immobilizing agents include C₁₆-C₁₈ fattyalcohol ethoxylates having an average degree of ethoxylation rangingfrom about 5 to about 20. Preferably, the fatty alcohols, fatty acidsand fatty alcohols are linear. Importantly, these preferred immobilizingagents such as the C₁₆-C₁₈ fatty alcohols increase the rate ofcrystallization of the composition causing the composition tocrystallize rapidly onto the surface of the substrate. Yet other typesof ingredients suitable for use as immobilizing agents, either alone, orin combination with the above-mentioned immobilizing agents, includewaxes such as carnauba, ozokerite, beeswax, candelilla, paraffin,ceresin, esparto, ouricuri, rezowax, isoparaffin, and other known minedand mineral waxes.

The Feces Modifying Agent may be delivered to the feces directly viatransfer of the FMA to the feces or it may initially transfer to thewearer's skin or other element of the article prior to transfer to thefeces. The carrier vehicle may be integral with the disposable articleor may constitute, or be component of, a separate article to be appliedto the wearer (preferably at least over the perianal region) prior to,or in place of, a diaper, training pant, underwear, or other article.

The means for joining the FMA to a carrier vehicle may include any meansknown in the art, such as adhesives (particularly water solubleadhesives), hydrogen bonding, releasable encapsulation, spraying,coating, and the like. Hydrogen bonding of the FMA to a substrate may beeffected by slightly wetting either the FMA or at least a portion of thesubstrate with water. Upon drying, the FMA is releasably affixed to thesubstrate (i.e., subsequent contact with liquid water will break thebond). This effect is enhanced for those FMAs which “gel” and becomesticky when wet (e.g., CMC, hydroxy propyl cellulose, alginic acid andderivatives, etc.). Wetting may be accomplished by subjecting either theFMA, substrate, or both to a high humidity environment (e.g., 80% RH orgreater) prior to or at the time of contact. Alternatively, water may besprayed, misted, or atomized over at least a portion of either the agentor substrates prior to or at the time of their contact. In such cases,the structure is preferably dried prior to incorporation into anarticle.

The FMA may contact the feces at or near the surface of the article(e.g., at the topsheet/feces interface), within the article (as in awaste management element 120 as described below), or at the body-sidesurface of the fecal mass (i.e., having first been transferred to theskin or other surface above the plane of the article). Typically, theFMA will contact the feces in the region of the article associated withthe wearer's anus (e.g., crotch region in a diaper context). The fecesmay alternatively contact the FMA as it passes through an orifice,flange, valve, or the like, at or near the anus of the wearer. In suchcases, the FMA may be expressed or drawn from the orifice or valve(e.g., from reservoirs) by the pressure of the passage of the feces asit extrudes from the body. The orifice may comprise a slit, slot, orperforation in a sheet, envelope, packet or other structure containingthe FMA or composition comprising a FMA disposed in proximity to theexit point of the feces from the body. The orifice may be initiallysealed by soluble film that is dissolved by contact with the feces,releasing the agent or composition. Alternatively, the orifice may beopened as the structure is deformed by passage or pressure of the feces.The feces pressure, in addition to body pressure and movement may aid inthe expression of FMA through the orifice to the feces.

In other preferred embodiments, the FMA may be associated with a gasketsuch as a leg cuff, waist barrier, waistband, waste pocket or with afeces spacing element. In embodiments wherein the FMA is associated witha gasketing element such as a leg cuff, waist barrier, or waist pocket,it is preferred that the FMA be associated with the portion of thegasket disposed closest to the exit point of the waste from the wearer(e.g., the anus for feces). In certain preferred embodiments, the FMA isreleasably attached to the surface of the gasket material so as topromote treatment of the feces and/or skin contacting the gasket. TheFMA may be releasably attached to the gasket surface via any of themeans described above or any other means known in the art. In otherembodiments, the FMA is releasably encapsulated at or near at least aportion of the gasket surface. In embodiments including feces spacingelements, any portion of the spacing element may comprise one or moreFMAs. The spacing element may be releasably coated with the agent asdescribed above or may comprise cells, packets, or pouches of the agentcovered, at least in part, with a water or feces-soluble film (asdescribed above).

The FMA may be delivered passively (e.g., the feces flows and contactsit during normal wearing conditions or the FMA is released to the fecesand/or skin as a result of normal wearer movement and/or pressure),actively (e.g., an element in the article responds to a signal anddelivers/releases the FMA to the feces), or via a secondary carrier(e.g., a powder or other skin care composition initially transferred tothe wearer's skin). Delivery of the FMA to the feces may occur as aresult of feces extrusion pressure, weight, temperature, enzymeactivity, water content, and/or pH; urine presence (e.g., urinetriggering release of the agent in response to or in anticipation of adefecation); body motions, pressure, or heat; or any other trigger orevent during the wear cycle of the article.

The FMA may be initially stored within or on the article or any portionthereof and subsequently released by any of the triggering eventsdescribed herein. In certain preferred embodiments, the FMA isreleasably encapsulated under a film, in cells, packets, envelopes andthe like so as to prevent migration and/or loss of the agent prior tothe article being insulted by feces and/or to aid in positioning the FMAfor contact with the feces during use. The film covering, cells,packets, or other “containers” for the agent may comprise awater-soluble film over at least the feces-contacting surface area ofthe container. The water from urine, feces, or other feces dissolves thefilm releasing the agent (i.e., triggering release) to contact and treatthe feces. An example of a water soluble film useful in the presentinvention is a polyvinyl alcohol film available as MONOSOL M7031 fromChris Craft Industrial products of South Holland, Ill. or HL1636 fromthe H. B. Fuller Co. of St. Paul, Minn. Alternatively, the film may besoluble only in the presence of certain fecal enzymes (like trypsin) orin certain pH ranges.

The release of the agent may be rapid (such as with an explosive gasrelease created by contacting urine or fecal water with a gas-evolvingcomposition) to embed or coat the feces with the agent. The gas evolvingcomposition may comprise particles, globules, etc. of one or moresubstances which evolve gas when mixed with or together in water (e.g.,sodium bicarbonate or sodium bicarbonate and citric acid). The particlesmay be embedded in a water soluble matrix (e.g., PVA). The FMA may bedisposed on or attached to the waste contacting surface of the film ormay be embedded in the water soluble film between the gas-evolvingcomposition and the feces contacting surface. Thus, for example, whenwater present in the feces dissolves the water-soluble film, thegas-evolving composition is activated (i.e., the component(s) mix withthe water) and gas is evolved rapidly, forcing mixing of the FMA and thefeces. The particles may comprise combinations such as citric acid andsodium bicarbonate which, when mixed with water, rapidly releases carbondioxide gas. Alternatively, the gas-evolving composition may comprisewater soluble capsules containing compressed gas and the FMA. Water fromthe feces which contacts the capsules can act to dissolve the film andrelease the gas explosively, again forcing mixing/embedding of the agentin the feces. Other compositions and gas-evolving or releasing systemsare contemplated and are included in the scope of this invention.

The article of the present invention may also include a responsivesystem 65 comprising a sensor 66, actuator 67, and stored energyemployed to transport the FMA to the feces, mix the agent with thefeces, or cause the agent to be expressed to contact the feces. Onepreferred embodiment comprises a shaped, compressed, macro-porous foam68, such as a reticulated polyurethane foam available as PG14848T20, andhaving 20 pores per square inch, from PCF Foam Corporation of Hamilton,Ohio, held in compression under a water-soluble polyvinyl alcohol filmas shown in FIG. 8. The foam 68 additionally comprises an FMA 75.Contact with fecal water results in dissolution of at least a portion ofthe PVA film resulting in a release of the stored mechanical energy inthe foam 68 and mechanical transport of the agent toward and into thefecal mass. In certain embodiments, mixing may occur via a mechanismincorporated in the article as described above (e.g., responsivesystem), mechanical action from the wearer's weight and/or motion,and/or the flow of feces during or subsequent to the act of defecation(especially low viscosity feces) to facilitate treatment of a greaterproportion of the fecal mass. Other responsive systems are described indetail in co-pending U.S. patent application Ser. No. 09/106,424entitled “Disposable Article Having A Discontinuous Responsive System”(P&G Case 7197) filed in the names of Roe et al. on Jun. 29, 1998; whichis hereby incorporated by reference herein.

In alternative embodiments, the FMA may be disposed on or associatedwith three-dimensional structures joined to or separate from otherelements of the absorbent article. For example, the absorbent articlemay include an element with protrusions, bumps, loops or the like whichhelp make the FMA available to contact the feces. In one preferredembodiment, “hairs” or strands of a hot melt resin including the fecesmodifying agent may be printed on a substrate 82. (An example of asubstrate including hairs comprising an FMA is shown in FIG. 7.) Theagent may be incorporated into the resin such that it moves to thesurface of the hairs and is available to the feces. Alternatively, theagent may be releasably bonded to the hairs via any of the techniquesdescribed above. Examples of suitable hairs and hooks are described inmore detail in U.S. Pat. No. 5,058,247 issued to Thomas et al. on Oct.22, 1991; U.S. Pat. No. 5,116,563 issued to Thomas et al. on May 26,1992; U.S. Pat. No. 5,326,415 issued to Thomas et al. on Jul. 5, 1994;and U.S. Pat. No. 5,762,645 issued to Peck et al. on Jun. 9, 1998. Eachof these patents is incorporated by reference herein.

In yet another embodiment, the FMA may be delivered to the feces and/orskin via a brush structure 60, one example of which is shown in FIG. 6.A brush structure may include a multiplicity of substantially alignedstrands, fibers, twisted yarns, strings, or other filamentous materialsaffixed to a substrate. The substrate may be planar, curved,ribbon-like, or have compound curvature and may be porous or non-porous.The brush filaments 62 are preferably bendable under the forces exertedby the feces during excretion so as to allow feces to readily passthrough or between the filaments 62. The brush filaments 62 may bepermanently or releasably affixed to the substrate. The filaments 62 maybe of plant or animal origin (e.g., cotton, etc.), cellulosic orsynthetic and may have different or similar lengths. The FMA isreleasably affixed to the filaments 62 of the brush structure 60 suchthat as the feces is pushed past the brush filaments 62, the agent isreleased and mixed with the feces. The brush structure 60 may beintegral with the article or may be separately applied to the wearer'sperianal region and may optionally comprise adhesive or other joiningmeans for adhering to the wearer or the article. The brush structure 60may be mounted over a spacer (as described above) having a void underthe filaments 62 so as to provide a space for the treated feces tooccupy.

The FMAs may also be delivered via the use of “smart” gels that undergoa phase transition or a geometric or volume change in response tocertain changes in pH, water content and/or some other trigger. Shapememory materials (i.e., metal alloys or plastics that return to apre-set geometry or shape when the temperature reaches a pre-determinedthreshold) may also be employed to move the agent into position tocontact or mix with feces, given the appropriate temperature change.Additionally, swellable materials, such as superabsorbent polymers orfoams, may be used to promote feces contact with the FMA. As a structurecontaining such swellable materials imbibes water, whether from feces orurine, it may transport a FMA associated with the body-facing surface ofthe structure toward a fecal mass and/or promote mixing with the feces.Foam-forming materials may also transport the FMA and promote contactwith feces in the article. In this case, the foam forming materialcomprises the FMA (or is associated with the agent) and coats the fecalmass as the foam is generated and its volume increases.

The FMAs may also be held on or within macro-particulate elements 170,as described below. These macro-particulate elements 170 may becontained in a waste management element 120, attached to a topsheet,cuff, or other feature of the article (releasably or not), or loose in aseparate article attached independently to the body. Some exemplarymacro-particulate structures are shown in FIGS. 2-4. Further, any of thestructures that hold, carry, deliver, or mix the FMA may compriseprotrusions or other three-dimensional geometries designed to increasecontact area of the FMA and the feces and/or to promote mixing.

In preferred embodiments, the FMA is associated with the topsheet of theabsorbent structure or article. However, the FMA may be associated witha layer underneath the topsheet, such as an acquisition layer. Inembodiments where the FMA is disposed in a layer underneath a topsheet,such as in a waste management element 120, feces must readily penetratethe topsheet, sublayer, and any other overlying structure for the agentto be available in an effective amount. Thus, it is preferred that suchstructures have an Acceptance Under Pressure of at least about 0.50g/cm2/J, and preferably at least about 1.0 g/cm2/J, as described in theTest Methods section below. In any case the agent is preferably locatednear the region of the article generally associated with the wearer'sperianal region.

As shown in FIG. 2, the present invention may include a waste managementelement 120. The waste management element 120 is designed to help managethe acceptance, storage and/or immobilization of the viscous fluidbodily waste. The waste management element 120 can be located anywherein the article, including the crotch region or either waist region, ormay be associated with or be included in any structure or element suchas the core 28, a leg cuff, etc. In preferred embodiments, the wastemanagement element 120 is located in the region of the article that isnear the wearer's perianal region when worn. This helps ensure that anywaste discharged is deposited on or near the waste management element120.

Although structures which accept, store and immobilize viscous fluidbodily wastes are preferred, in certain embodiments of the presentinvention, the waste management element 120 may comprise only anacceptance element, a storage element or an immobilization element, ormay include a combination of two of the elements, but not the third.Also, in certain embodiments, one element may perform more than onefunction (e.g., a storage element may perform both the storage andimmobilization functions). For example, the absorbent article of thepresent invention may include an acceptance and a storage element tomanage viscous fluid bodily wastes without a separate immobilizationelement, per se.

The acceptance element 150 may be any material or structure capable ofaccepting bodily exudates. (As used herein, the term “accept” or“acceptance” refers to the penetration of a structure by materialsdeposited thereon. Penetration is defined by the passage of materialsthrough the surface of the structure upon which the material wasdeposited. Penetration of nonuniform structures can be defined as thepassage of a material through a plane defining the surface upon whichthe material was deposited.) The acceptance element 150 may include asingle material or a number of materials operatively associated witheach other. Further, the acceptance element 150 may be integral withanother element of the diaper 20 or may be one or more separate elementsjoined directly or indirectly with one or more elements of the diaper20. Further, any or all of the acceptance element 150 may be removablefrom the absorbent article for separate disposal, if desirable.

The acceptance element 150 is preferably disposed at least partially inthe crotch region 37 of the diaper 20 adjacent the body surface 47 ofthe core 28, although in some alternate embodiments, the acceptanceelement 150 may include at least a portion of a leg cuff, waistband,fecal waste containment pocket, or the like, or may be operativelyassociated with any such features. Preferably, at least the portion ofthe acceptance element 150 located in the region of diaper 20 which isnear the anus of the wearer during use is unobstructed by overlyinglayers of structures, such as the topsheet 24. Thus, it may be desirableto cut out a portion of the topsheet 24 in the region of the articleintended to be located near the wearer's anus and to provide anacceptance element 150 as the body-side liner in that region.Alternatively, any or all of the topsheet 24 may be made or treated toact as the acceptance element 150. In one embodiment, as shown in FIG.2, the acceptance element 150 includes at least a portion of thetopsheet 24. In other embodiments, the acceptance element 150 mayinclude at least a portion of other elements of the diaper such as theabsorbent core 28 or the storage element (described below).

In some embodiments, it may be desirable to provide the diaper 20 withdifferent acceptance capability in different portions of the diaper.This may be accomplished by providing different acceptance elements inthe different regions of the diaper 20 or by providing a singleacceptance element 150 which has been manufactured or treated to haveregions of differing acceptance characteristics. Further, the acceptanceelement 150 may be elevated above the plane of the body-facing surfaceof the article so as to be in better control of exuded viscous fluidbodily wastes. In some embodiments, it may even be desirable to have theacceptance element 150 in contact with skin of wearer in proximity ofthe viscous bodily waste source (e.g., the perianal region).

Suitable materials and structures for use as the acceptance element 150may be absorbent or nonabsorbent and may include apertured nonwovenwebs, apertured films, apertured formed films, scrims, woven webs,scrim, netting, macroporous thin foams, and the like. One particularlypreferred material is a woven nylon netting having a basis weight ofabout 27.3 g/m², an effective open area of about 60% and a primaryaperture size of about 5.0 mm² (effective open area and primary aperturesize are measured as described in U.S. Pat. No. 5,342,338, which ishereby incorporated by reference herein). One such material is availableas a Toy Tub Bag from Dollar Tree Dist., of Norfolk, Va. Further, theacceptance element 150, or any portion thereof, may be coated with alotion or other known substances to add, enhance or change theperformance or other characteristics of the element. For example, theacceptance element 150 may be hydrophobic or hydrophilic or treated tobe either.

As described above, the FMA may be associated with the acceptanceelement preferably in the wearer's perianal region. In certain preferredembodiments, the FMA is releasably attached to the acceptance element bythe means described above. In alternative embodiments, the agent isreleasably encapsulated in a structure associated with at least aportion of the acceptance element 150. The agent may be released to thefeces upon contact with water, heat, or pressure/wearer motion. Theagent may alternatively first be transferred to the wearer's skin oranother portion of the article (e.g., leg cuff) prior to deposition ontothe feces. For example, urine may effect the release of a releasablyencapsulated agent or composition. The agent may transfer to thewearer's skin by body contact and/or pressure. Upon subsequent contactwith feces, the agent will transfer from the skin to the surface of thefeces.

Once viscous bodily waste has penetrated the waste management element120, it is desirable to store or hold the waste away from the wearerduring the remainder of the wearing cycle and away from the caregiverduring the changing process. As used herein, the term “store” refers tothe physical separation of material deposited in a diaper from thebody-facing surface of the article such that the material deposited inthe diaper is not immediately in contact with or accessible to thewearer's skin. Adequate storage capacity is essential to reduce theprobability of leakage and the area of skin contaminated by viscousbodily waste because viscous bodily waste that has been stored is lesslikely to be available to the body-facing surface of the structure forleakage and migration within the article.

The storage element 152 may be located anywhere in the diaper 20.However, it is preferred that the storage element 152 be operativelyassociated with the acceptance element 150 and/or topsheet 24, if any,such that viscous bodily waste accepted by the acceptance element 150may enter the storage element 152. (Embodiments are contemplated whereinthe diaper 20 has no topsheet 24 or acceptance element 150. In suchcases, the bodily waste may enter the storage element 152 directly,without passing through any overlying structure.) In any case, it ispreferred that the storage element 152 be located in the region of thediaper 20 which is located near the wearer's anus when the diaper 20 isworn. Accordingly, it is preferred that at least a portion of thestorage element 152 be disposed in the crotch region 37 of the absorbentarticle. However, in some alternate embodiments, the storage element 152may include at least a portion of either waist region, a leg cuff, thewaistband, a fecal waste containment pocket, or the like, or may beoperatively associated with any such features. Further, the storageelement 152 may be elevated above the plane of body-facing surface ofthe article so as to be in better control of exuded viscous bodilywastes. In some embodiments, it may even be desirable to have thestorage element 152 in contact with skin of wearer in proximity of theviscous bodily waste source (e.g., the perianal region).

The storage capability of the storage element 152 may be uniform or mayvary throughout the diaper 20. Such variations may be accomplished byemploying multiple storage elements 152 in the diaper 20 or by providinga single storage element 152 with regions of different storageproperties. Further, any or all of the storage element 152 may beremovable from the absorbent article for separate disposal, if desired.

The storage element 152 may be any material or structure capable ofstoring bodily exudates, as described above. Thus, the storage element152 may include a single material or a number of materials operativelyassociated with each other. Further, the storage element 152 may beintegral with another element of the diaper 20 or may be one or moreseparate elements joined directly or indirectly with one or moreelements of the diaper 20. In one embodiment, as shown in FIG. 2, thestorage element 152 includes a structure that is separate from the core28. However, embodiments are contemplated wherein the storage element152 includes at least a portion of the core 28.

Suitable materials for use as the storage element 152 may include largecell open foams, macro-porous compression resistant nonwoven highlofts,large size particulate forms of open and closed cell foams (macro and/ormicroporous), highloft nonwovens, polyolefin, polystyrene, polyurethanefoams or particles, structures comprising a multiplicity of verticallyoriented looped strands of fibers, absorbent core structures describedabove having punched holes or depressions, and the like. (As usedherein, the term “microporous” refers to materials which are capable oftransporting fluids by capillary action. The term “macroporous” refersto materials having pores too large to effect capillary transport offluid, generally having pores greater than about 0.5 mm in diameter andmore specifically, having pores greater than about 1.0 mm in diameter.)One embodiment includes a mechanical fastening loop landing element,having an uncompressed thickness of about 1.5 millimeters available asXPL-7124 from the 3M Corporation of Minneapolis, Minn. Anotherembodiment includes a 6 denier, crimped and resin-bonded nonwovenhighloft having a basis weight of 110 grams per square meter and anuncompressed thickness of 7.9 millimeters which is available from theGlit Company of Wrens, Ga. The storage element 152, or any portionthereof, may include or be coated with a lotion or other knownsubstances to add, enhance or change the performance or othercharacteristics of the element.

An alternate embodiment of a storage element 152 includes amacro-particulate structure 170 comprising a multiplicity of discreteparticles 172, nonlimiting examples of which are shown as FIGS. 2-4. Themacro particles 172 preferably have a nominal size, preferably betweenabout 1.0 mm and about 25.4 mm, and more preferably between about 2 mmand about 16 mm. However, particles as small as 0.5 mm and smaller, andparticles larger than about 25.4 mm are contemplated. Particles having anominal size of about 1.0 mm or greater are those which are generallyretained on the surface of a U.S. Standard No. 18 mesh sieve screen.Particles having a nominal size of less than about 25.4 mm are thosewhich generally pass through a U.S. Standard 25.4 mm sieve screen.Particles having a nominal size of 16 mm or greater are those which aregenerally retained on the surface of a U.S. Standard No. 16 mm sievescreen. The nominal particle size is measured prior to incorporating theparticles into a storage element 152 for testing or use. Particleshaving a nominal size of 8 mm or greater are those which are generallyretained on the surface of a U.S. Standard 8 mm sieve screen.

The macro-particulate structure 170 may include any number of particles172. Further, the particles 172 may be unjoined and free to move withinthe structure 170 or may be joined to each other by any known means.Alternatively, the structure 170 may include an external support, suchas a meltblown hot-melt glue, a web, a netting, a scrim, a thread orother adhesive or nonadhesive entangling supports. Any of the particles172 may also be joined with any other portion of the diaper structure,such as the topsheet or the core. The particles 172 may also beconstrained in patterned, three-dimensional regions such as pleats,“pillows”, and pockets.

The individual particles 172 may be made from any material suitable foruse in absorbent articles, including the materials described above withregard to the absorbent core 28 or the storage element 152. Thematerials used in the particles 172 may be absorbent, nonabsorbent,microporous, macroporous, resilient, nonresilient, etc. or may have anyother desirable characteristic. Examples of macroporous absorbentmaterials suitable for use in the particles 172 include highloftnonwovens, open cell foams, bundles of fibers, sponges and the like.Other absorbent materials include cellulosic batts, capillary channelfibers, osmotic storage materials such as superabsorbent polymers, etc.Nonabsorbent particles 172 may comprise plastic, metal, ceramic, glass,closed cell foams, column packing materials, synthetic fibers, gels,encapsulated gas, liquids and the like. Further, any or all of theparticles 172 may include odor absorbents, lotions, skin careformulations, antimicrobials, pH buffers, enzyme inhibitors, and thelike.

The storage element 152 may comprise a single type of particle 172(size, shape, material, etc.) or may include a mixture of differentparticles 172. The mixture may be homogeneous; heterogeneous, as whenparticles 172 having different properties are disposed in certain areasof the storage element 152; layered; or any other desirableconfiguration. In some embodiments, more than one type of mixture may beemployed (e.g., macroporous and nonabsorbent particles 172 may behomogeneously mixed in one layer while another layer includes onlyabsorbent particles.) Different layers of particles may be directlyadjacent each other or may be separated by one or more materials, suchas netting, scrim, nonwoven or woven webs, film, foam, adhesive, and thelike.

The macro-particulate structure 170 preferably includes a continuousinterstitial void space 174 that is defined by the space between theparticles 172. By varying the size and/or shape of the particles 172,the interstitial void space 174 can be controlled. The particles may beof any known shape, including spheres, oblate spheroids, rectangular andpolygonal solids, and the like.

In addition to its storage function, the storage element 152 maytransport viscous bodily waste within the absorbent article 20 indirections generally parallel to the plane of the backsheet 26. Thetransport may be active, such that capillary or other forces result inthe movement of the viscous bodily waste or components thereof (e.g.,free water). In other embodiments, the transport may be passive wherebyviscous fluid bodily waste or components thereof move through thestructure under the influence of externally applied forces, such asgravity, wearer pressure or wearer motion. In the case of passivetransport, the storage element 152 should have relatively large,interconnected channels, or the like, such that the viscous bodily wastemay readily move through the structure with minimum energy input.

The FMA of the present invention may be associated with any portion ofthe storage element 152, including the macro-particulate structures. Incertain preferred embodiments wherein the storage element 152 has raisedregions, the FMA is associated with the raised regions of the element.Viscous bodily waste penetrating the acceptance element may contact theFMA and carry it to the “lower” regions of the storage element 152,providing enhanced mixing. For example, the raised tops of loop typestorage elements may be slightly wetted or dampened and subsequentlycontacted with the FMA to releasably affix the FMA to the raisedportions, and subsequently dried. The releasable attachment may also beeffected via water soluble adhesives. In macro-particulate embodiments,the agent may be held within a macro-porous particle. In alternateembodiments, the agent may be releasably affixed to the exterior surfaceof the particulate elements. Fecal contact with the FMA preferablyeffects a release of the agent from the storage element and allowsmixing with the feces.

Viscous bodily waste that is accepted by, or penetrates, the absorbentarticle is preferably also retained in the diaper away from the wearer.One preferred way to retain bodily waste, especially viscous bodilywaste, is to immobilize the waste in a location away from the wearer. Asused herein, the term “immobilize” refers to the ability of the materialor structure to retain stored viscous bodily waste under an appliedpressure and/or the influence of gravitational forces.

The immobilization element 154 may be any material or structure capableof reducing the proclivity of viscous bodily waste that has penetratedthe immobilization element 154 from leaving the structure. Thus, theimmobilization element 154 may include a single material or a number ofmaterials operatively associated with each other. Further, theimmobilization element 154 may be integral with another element of thediaper 20 or may be one or more separate elements joined directly orindirectly with one or more elements of the diaper 20. For example, theimmobilization element 154 may be an unjoined layer of material disposedunder the storage element 152 or may include all or a portion of thestorage element 152 which is able to immobilize and retain viscousbodily waste, as described above. In any case, it is preferred that theimmobilization element 154 be operatively associated with the storageelement 152 and the acceptance element 150. This is necessary to ensurethat viscous bodily waste accepted and/or stored by the article passesinto or comes in contact with the immobilization element 154.Accordingly, it may be desirable to locate the immobilization element154 below the storage element 152 and the acceptance element 150, in atleast a portion of the crotch region 37 of the article. However, asnoted above if the storage element 152 has transportation capabilities,the immobilization element 154 may be located anywhere in the diaper 20such that the viscous fluid bodily waste accepted and/or stored can betransported to the immobilization element 154. Further, as with theacceptance and storage elements 150 and 152, the diaper 20 may haveuniform or nonuniform immobilization capability. Thus, one or moreimmobilization elements 154 may incorporated in the article havingregions of different immobilization and/or retention performance.Further, any or all of the immobilization element 154 may be removablefrom the absorbent article for separate disposal, if desirable.

Suitable materials for use in the immobilization element 154 includemicroporous foams, superabsorbent polymer particles or fibers,cellulosic fibers, capillary channel fibers, entangled synthetic fiberbatts and the like. Some preferred materials include foam absorbentmaterials such as those described in U.S. Pat. Nos. 5,260,345;5,387,207; and 5,625,222. Other preferred materials include absorbentgelling materials such as those described in U.S. Pat. No. 5,147,345entitled “High Efficiency Absorbent Articles For IncontinenceManagement” issued to Young et al. on Sep. 15, 1992. Each of thesepatents is hereby incorporated by reference herein.

The FMA may be associated with the immobilization element 154. In theseembodiments, the modifying agent may act to enhance the efficacy andefficiency of the immobilization element 154 by facilitating the removalof water from the feces, and thereby increasing the speed of theimmobilization process and/or reducing the final mobility of theremaining solid fraction of feces. The FMA may alternatively serve toincrease the viscosity of the feces within the immobilization via adirect thickening mechanism. The FMA may be loosely associated with theimmobilization element or may be releasably affixed (i.e., such thatfeces water may effect its release) to the immobilization element 154.

The article of the present invention can also improve the removabilityof feces or other bodily exudates from the wearer's skin, and henceenhance the efficacy of skin cleanup after excretion. Generally, fecesthat are very soft or liquid (i.e., have low Hardness values) arerelatively easy to remove from the skin since they have low viscositiesand high water content. Feces having high Hardness values (i.e., aresolid) are also relatively easy to remove since, being solid-like, theydo not adhere aggressively to the skin. Pasty feces (i.e., those havingintermediate Hardness values, often in the range of about 25 to about800 grams), however, are relatively difficult to remove from the skin.

As used herein, “pasty feces” refers to a relatively wide range ofconsistency generally characterized by a lack of spontaneous flow undergravitational forces, but a readily plastic flow response to pressuressimilar to those applied by a baby sitting on a diaper, and is closelyrepresented by Analog B and Fluorescing Analog B, as described herein,which is used in the cleaning efficacy measurements described below.Pasty feces is generally difficult to remove from the skin of a wearerbecause the internal cohesive force is lower than the adhesion force ofthe pasty feces to skin. This results in a “shearing” effect (i.e., thefeces fails cohesively, leaving the remaining feces on the skin) whenthe caregiver attempts to remove the feces, such as with a disposablewet wipe. This forces the caregiver to repeat the wiping process inorder to effect a more complete cleaning. In the case of baby diapers,most parents will continue to wipe until no visible residue can be seeneither on the baby's skin or the last wipe used. This process can bequite tedious and time-consuming and may require the use of a largenumber of wipes, increasing the cost of the cleanup. Additionally, ithas been found that residual, invisible, “micro-level” contamination, asdetected by residual fecal enzymes and coliform bacteria, remains onvirtually all babies following a feces cleanup. Measurable residualfecal contamination has been found on babies' skin after cleanup withvarious cleaning protocols and aids, including disposable wet wipes,wetted paper towels and cotton balls, and baths with water and/or soap.The residual fecal contamination generally comprises all or most of thecomponents of feces, including enzymes (e.g., trypsin, chymotrypsin,leucine aminopeptidase, and lipase), bile salts, and microorganisms(e.g., Candida albicans and fecal coliforms including E. coli), many ofwhich are implicated in skin irritation such as redness, diaperdermatitis, and Candidiasis. Further, high levels of residual fecalcontamination have been found in irritated areas of diapered skin. It ishighly desirable to provide an enhanced level of feces removability fromthe skin so as to obtain skin health, convenience, and cost benefits.

Modifying pasty feces by either significantly increasing or decreasingits hardness, for example by employing FMAs in the receiving article asheretofore described, will generally result in improved fecesremovability and enhanced cleaning efficacy. The article also preferablyincludes a lotion or other skin care composition, either separately oras a carrier for the FMA, disposed on an element or elements of thearticle that may contact the wearer's skin and effect transfer of atleast a portion of the lotion or other skin care composition to theskin, such transfer ideally occurring prior to elimination of bodilywaste. For example, in regard to a diaper, incontinence brief, orsanitary napkin, the lotion or other skin care composition wouldpreferably be disposed on a portion of the topsheet, cuff, wastereceiving pocket (if present), or other element in the crotch region ofthe article so as to be located near and transfer to the perianal regionof the wearer. Examples of suitable lotions and other skin carecompositions are described herein.

An in vitro test method, described in detail in the Test Methods sectionbelow, has been developed to simulate macro and microlevel fecesremovability in the context of a cleaning regimen. Feces removabilitymay be characterized in terms of the degree or amount of residual feceson the wearer's skin (i.e., residual contamination). An enhanced levelof removability results in, and may be quantified by, a reduction in thelevel, including area and/or mass of residual fecal contamination. Thetest employs a synthetic fecal analog having viscous, elastic, andadhesion properties representative of actual infant pasty feces. Thetest additionally includes a fluorescent marker incorporated into thefecal analog, a synthetic skin analog, and a wiping device. Fecesremaining on the skin analog after a defined wiping protocol is reportedin terms of the area and intensity (i.e., the relative amount ofresidual fecal analog per unit area of skin) of the fluorescence on theskin analog under a ultraviolet light. As used herein, the term “WasteContamination Area” refers to the contaminated area of the skin analogmeasured after the defined wiping protocol. As further used herein, theterm “Waste Contamination Mass” refers to the relative mass of fecesremaining on the skin analog, calculated using “Waste ContaminationArea” and the amount of residual feces per unit area of skin (i.e., asmeasured by the ultraviolet light intensity data). The units associatedwith Waste Contamination Mass are “mass units” calculated as describedin more detail in the Calculations section, below. Exemplary data arepresented in Table VIII.

Preferred disposable articles of the present invention include one ormore compositions which enhance the removability of feces from the skinas determined by a Waste Contamination Area of less than about 15 cm².More preferred disposable articles of the invention include one or morecompositions which enhance the removability of feces from the skin asdetermined by a Waste Contamination Area of less than about 12 cm². Evenmore preferred disposable articles of the invention include one or morecompositions which enhance the removability of feces from the skin asdetermined by a Waste Contamination Area of less about 10 cm².

Preferred disposable articles of the present invention include one ormore compositions which enhance the removability of feces from the skinresulting in a Waste Contamination Mass of less than about 14 massunits. More preferably, the disposable article include one or morecompositions which provide enhanced removability of feces from the skinresulting in a Waste Contamination Mass of no less than about 10 massunits. Even more preferably, the disposable article include one or morecompositions which provide an enhanced removability of feces from theskin resulting in a Waste Contamination Mass of less than about 8 massunits.

The improvement in feces removability (which relates to theeffectiveness of the article in enhancing the cleanability of feces fromthe wearer's skin and the reduction in residual contamination) isillustrated with several examples in Table VIII below. The lotioncomposition referenced in Table VIII may be prepared in accord withExample 5 of U.S. Pat. No. 5,643,588, varying the weightpercentage/constituents of the lotion composition to be consistent withthose described in Table VIII.

TABLE VIII Waste Waste Contamination Contamination Mass Skin AnalogTreatment Area (cm²) (mass units) Comparative Examples (A) No treatment27.5 27.3 (B) lotion (57% petrolatum, 42% 28.0 27.7 stearyl alcohol, 1%aloe extract - see above) (C) Johnson's Baby Powder (see Table 18.6 17.1II above) (D) Johnson's Baby Powder (see Table 21.1 19.2 II above) pluslotion (57% petrolatum, 42% stearyl alcohol, 1% aloe extract) Examplesof the Present Invention (E) FMA (alginic acid, Ca-ammonium 7.4 6.7salt - see Table VI above) plus lotion (57% petrolatum, 42% stearylalcohol, 1% aloe extract) (F) FMA (alginic acid, Ca-ammonium 10.1 9.0salt - see Table VI above) without lotion (G) FMA (carboxymethylcellulose - 7.9 7.3 see Table V above) without lotion

As can be readily seen above in Table VIII, a lotion composition andbaby powder provide at best only a modest removability/cleaning benefitversus an untreated skin. On the other hand, in Example (E) wherein thearticle delivers an FMA composition to the feces and/or skin in additionto the lotion composition, a much more significant and unexpectedbenefit level was achieved. This simulates a skin care composition suchas a lotion transferred to the wearer's skin by, for example, a topsheetcomprising a lotion, as described herein, applied to the wearer-facingside of the topsheet and a subsequent release, whether instantaneouslyor over an extended period of time, of an FMA to contact the feces andsurrounding skin area. Examples (F) and (G) of Table VIII illustratethat the benefits of the invention may also be obtained through the useof FMA compositions without lotion.

Preferred Embodiments

As noted above, the present invention is applicable to many types ofabsorbent articles such as diapers, training pants, incontinence briefs,incontinence undergarments or pads, inserts including absorbent inserts,diaper holders and liners, feminine hygiene garments, wipes, disposablemops, bandages and the like and separate articles attached to a wearerover the perianal region such as colostomy bags. Thus, the followingexamples of preferred embodiments of the present invention should notconstrued to limit the scope of the invention.

One preferred embodiment of the present invention is the absorbentarticle, in the form of diaper 20, illustrated in FIG. 2. The diaper 20has a first waist region 36, a second waist region 38 and a crotchregion 37 located between the first waist region 36 and the second waistregion 38. The diaper 20 includes a topsheet 24, a backsheet 26 and anabsorbent core 28 disposed between the topsheet 24 and the backsheet 26.The topsheet 24 is disposed in at least a portion of the first waistregion 36 adjacent the body facing surface 47 of the core 28. The diaper20 also includes an acceptance element 150 joined with the topsheet 24and extending longitudinally away from the topsheet 24 through at leasta portion of the crotch region 37 and at least a portion of the secondwaist region 38. The acceptance element 150 includes a woven nettingavailable as a Tub Toy Bag from Dollar Tree Dist., of Norfolk, Va.

The diaper 20 preferably further includes a storage element 152 locatedbetween the acceptance element 150 and the backsheet 26. The storageelement 152 is located in at least a portion of the crotch region 37 andat least a portion of the second waist region 38. In this embodiment,the storage element 152 includes a macro-particulate structure 170comprising particles 172. Specifically, the macro-particulate structure170 includes about two grams of the scrubber particles mixed with about0.35 grams of strips of foam absorbent material having a basis weight of45 grams per square meter, as described in U.S. Pat. No. 5,260,345. (Thescrubber particles can be made by cutting the abrasive nonwoven highloftside of a scrubbing pad (e.g., available as Light Duty Scrubbers #00065from the Libman Company of Arcola, Ill.) into particles of about 8mm×about 7 mm×about 5 mm.) The strips have dimensions of about 19millimeters in length, 6.4 millimeters in width, and 2 millimeters inthickness. The scrubber particles are distributed over a 2.5 inch×6.4inch (16 square inch) area disposed along the longitudinal axis of thearticle of approximately 0.8 mm thick “thin until wet” foam absorbentmaterial (described in U.S. Pat. No. 5,387,207 which is incorporatedherein by reference) having a basis weight of 126 grams per squaremeter. The scrubber particles are relatively homogeneously mixed withthe absorbent foam strips and are free to move within the areacircumscribed by the layer of “thin-until-wet” absorbent foam material.The particles and strips are preferably not bonded to the woven nettingtopsheet or any other layer. A FMA is preferably associated with theparticulate elements of the storage layer via any of the means describedherein. The acceptance element 150 is bonded to the underlying layersoutside the periphery of the layer of “thin-until-wet” absorbent foam.

Another preferred embodiment of the present invention is the absorbentarticle, in the form of diaper 200, illustrated in FIG. 11. Thewearer-facing surface of the topsheet of this embodiment comprises thelotion composition (57% petrolatum, 42% stearyl alcohol, 1% aloeextract) referenced above in Table VIII. Lotion 186 may be applied tothe topsheet 24 as described in connection with Example 5 of U.S. Pat.No. 5,643,588, referenced herein relative to lotioned topsheets, andwhich is incorporated herein by reference.

As shown in FIGS. 11 and 12, the diaper 200 also includes an effectiveamount (about 3.5 grams) of an alginic acid, ammonium-calcium saltcomposition 190 (Sigma A-7253, available from Sigma Chemical Co., St.Louis, Mo.), described above in connection with Tables VI and VIII as anFMA, applied to a carrier 180. Carrier 180 comprises a wearer-facingfibrous loop material 182 which may be bonded to an optionalthermoplastic backing 184 made, for example, from polypropylene.Materials of this nature are described in PCT Patent Application SerialNo. US97/20840 entitled “Disposable Absorbent Article Having FecalManagement Member”, filed Nov. 14, 1997, which is incorporated herein byreference. The alginic acid, ammonium-calcium salt 190 is releasablyaffixed to a loop material 182 via hydrogen bonding. Such hydrogenbonding may be obtained by applying a fine water mist to thewearer-facing surface of the loop material, applying the alginic acid,ammonium-calcium salt to the wearer-facing surface, and subsequentlydrying the structure. Excess or additional alginic acid,ammonium-calcium salt may be disposed in any voids 185 in the loopmaterial 182. Carrier 180 is joined to the wearer-facing surface of thetopsheet 24 in at least a portion of the crotch region associated withthe wearer's perianal region using adhesive, or any other suitableattachment means or combinations of means such as heat bonds, pressurebonds, ultrasonic bonds, dynamic mechanical bonds. Lotion composition188 may also be applied to at least a portion of the carrier, such as tothe valleys 186 between loops in loop material 182.

In yet another embodiment, the alginic acid, ammonium-calcium salt isencapsulated in a sealed envelope, at least a portion of the body-facingside of which comprises a soluble film (e.g., MONOSOL 7031, describedabove). The envelope containing the alginic acid salt may be affixed tothe topsheet surface of the foregoing diaper example or may be disposedunder a portion of the topsheet 24 comprising apertures of sufficientsize (e.g., at least about 1 mm in their longest dimension). Water (froma urination, for example) or another constituent of a body exudate willdissolve at least a portion of the soluble region of the envelope,releasing the alginic acid to the wearer-facing side of the topsheet 24,and subsequently to the skin and/or feces. Alternatively, the alginicacid, ammonium-calcium salt (or other FMA composition)/carrier structuremay include a responsive system as described in more detail abovecomprising a compressed resilient element (e.g., a macroporous foam or ahigh internal phase emulsion foam as described in the above-referencedU.S. Pat. Nos. 5,260,345 and 5,625,222) comprising the FMA held at ornear the wearer-facing side of said resilient element under vacuum in abag, at least a portion of which comprises a soluble film (e.g., MONOSOL7031). Upon contact with water (e.g., in urine), the soluble film willdissolve, releasing the vacuum and allowing the compressed resilientelement to expand and deliver the FMA to the skin and/or feces.

In still another embodiment, as shown in FIG. 5, the absorbent articleof the invention may be an insert 21, a sanitary napkin, or otherabsorbent article which is intended to be applied separately to thewearer or to be placed in the wearer's underwear, an outer cover or thelike. Thus, the insert 21 is generally not intended to take the form ofa pant, but rather is to be used in conjunction with a pant or otherstructure which holds the insert 21 in place about the wearer. Theabsorbent insert 21 has a pair of opposed end regions 135 separated by acentral region 137 and includes an absorbent assembly 27 which mayinclude an absorbent core 28, an acceptance element 150, a storageelement 152, an immobilization element 154 and/or the alginic acid,ammonium-calcium salt/loop carrier structure as described above. Theattachment element 41 may comprise adhesive, cohesive, hooks, snaps,buckles, buttons, ties, magnetic, electronic and/or any other know meansfor attaching absorbent articles to undergarments.

TEST METHODS

Viscosity

The viscosity may be determined by a controlled stress rheometer. Asuitable rheometer is available from T. A. Instruments, Inc. of NewCastle, Del., as model number SC²100. The rheometer utilizes a stainlesssteel parallel plate fixture. The rheometer has a rigid horizontal firstplate onto which the sample is placed and a second plate mounted overthe first plate such that the axis of said second plate is perpendicularto the first plate. The second plate is 2 or 4 centimeters in diameter.A two centimeter (2 cm) parallel plate is used for firm, pasty, orhighly mucousy samples, while the four centimeter (4 cm) parallel plateis used for very runny or “water-like” fecal samples. The first andsecond plates are spaced apart up to 2000 microns during the measurementprocess. The second plate is connected to a drive shaft for axialrotation. The drive motor and strain sensor are also mounted on thedrive shaft.

A suitable sample (typically 2 to 3 grams) of an analog to be tested iscentered on the first plate and generally centered beneath the axis ofthe second plate. Prior to the test, any large pieces of undigested foodmaterial (e.g., seeds) are removed. The first plate is raised intoposition. Excess amounts of the sample which are displaced beyond thediameter of the second plate are removed using a spatula. Water is thenmisted around the edges of the sample to prevent edge effects due tomoisture loss during the measurement process. A programmed applicationof a shear stress, from 50 to 50,000 dynes/cm² for pasty and firmsamples, is applied to the sample by the rheometer. For runny and waterysamples, a shear stress range of 5 to 5000 dynes/cm² was used instead.The data is fitted to a power law function where the apparentviscosity=k j^((n−1)), k=consistency (units of cP×sec^((n−1)), j=shearrate (Units of 1/sec), and n=shear index (dimensionless). Therefore,when j=one 1/sec, the viscosity=k. (The plates are maintained at 35degrees C. throughout the test.)

Hardness Method

Hardness is measured using a Stevens-Farnell QTS-25 Texture Analyzer,model 7113-5 kg, and associated software on an Intel-based machinehaving a 486 processor or higher. A ½ inch stainless steel sphericalprobe and an analog receptacle are provided. A suitable probe is theTA18 probe available from Leonard Farnell Co. of Hatfield, England. Theanalog receptacle can be made by cutting a 7 milliliter linear lowdensity polyethylene scintillation vial (having an inside diameter of0.55 inches+/−0.005 inches) to about 16 millimeter length. Suitablevials are available from Kimble Glass Company of Vineland, N.J. as#58503-7 vials. The analog receptacle is filled to the top edge (level)with the analog (Analog A or B, as described below) or feces to betested. If a modification agent is to be evaluated, the sample isprepared via the Sample Preparation Method described below. The vial iscentered under the ½ inch spherical stainless steel probe. The probe islowered such that it just contacts the surface of the analog in thevial. The probe 162 is moved downward 7 millimeters at about 100millimeters per minute and then stopped. The Hardness is the maximumrecorded resistive force encountered by the probe on its 7 millimeterstroke. (The temperature of the room and the analog should be betweenabout 65 to 75 degrees Fahrenheit during the course of the measurement.)For reference, Hardness has been found to relate strongly to the complexmodulus of the material, which is a combination of the viscous andelastic moduli of the material.

Method for Making Analog A

1.5 grams of Ultra Dawn dishwashing liquid (available from the Procter &Gamble Co, Cincinnati, Ohio) is added to an empty metal mixing bowl. 10grams each of Feclone FPS-2 and Feclone FPS-4 are added into the bowlcontaining the Dawn. (Both Feclone materials are available fromSiliclone Studios, Valley Forge, Pa.) Then 200 milliliters of distilledwater heated to 200° F. is added to the mixing bowl. The resultantmixture is then carefully stirred by hand, to avoid introducing airbubbles to the mixture, using a rubber or plastic spatula untilhomogenous, (usually about 3-5 minutes). If prepared properly, theAnalog A will have a Hardness between about 7 and 10 grams as measuredby the above Hardness Method.

Method for Making Analog B

5 grams each of FECLONE BFPS-4, FECLONE BFPS-6, and FECLONE BFPS-7 areadded into an empty metal mixing bowl. (the FECLONE materials areavailable from Siliclone Studios, Valley Forge, Pa.). Then 0.67 grams ofCarbopol 941 (available from the B.F. Goodrich Corp. of Brecksville,Ohio) is added into the bowl and these four ingredients are stirreduntil they are homogeneously mixed using a rubber or plastic spatula toensure adequate dispersion of the powder materials upon mixing in water.Next, 60 milliliters of water heated to 200° F. is added to the mixingbowl. The resultant mixture is mixed manually, and is stirred carefullyto avoid introducing air bubbles to the mixture, using a rubber orplastic spatula until homogenous (usually about 3-5 minutes). Ifprepared properly, the Analog B will have a Hardness between about 600and 650 grams.

Method for Making Fluorescing Analog B

A fluorescing version of analog B to be used in the Waste ContaminationMethods below is made by following the procedure described for Analog Babove, with the exception that 0.40 grams of a fluorescing agent,Brightener 49-Tinopal CBS-X, available from Ciba Specialty ChemicalsCorp. of High Point, N.C., is added to and mixed with the dry FeClonemixture and Carbopol 941 prior to the addition of the water as describedin connection with Analog B above.

Method for Making Analog C

Analog C is a fecal material analog made by mixing 10 grams of Carbopol941 available from the B.F. Goodrich Corporation of Brecksville, Ohio,or an equivalent acrylic polymer in 900 milliliters of distilled water.The Carpobol 941 and distilled water are weighed and measuredseparately. A 3-bladed marine-type propeller having a 2 inch diameterpaddle, (available from VWR Scientific Products Corp. of Cincinnati,Ohio, Catalog #BR4553-64, affixed to a ⅜″ stirring shaft BR4553-52), isused to stir the distilled water. The propeller speed should be constantat 450 rpm during mixing. The mixer should form a vortex withoutsplashing. The Carbopol is slowly sieved into the water so that it isdrawn into the vortex and mixed without forming white clumps, or “fisheyes”. The mixture is stirred until all of the Carbopol has been added,and then for a period of 2 minutes thereafter. The sides of the bowlcontaining the mixture should be scraped and the bowl should be rotatedas needed to achieve a homogeneous mixture. (The mixture will likely beslightly cloudy with air bubbles). One hundred grams of a 1.0 Nvolumetric NaOH solution, available from J. T. Baker Co., Phillipsburg,N.J., is then slowly measured into the mixture and the mixture isstirred until homogeneous. The mixture should become thick and clear.The mixture should be stirred for 2 minutes after the addition of thealkali solution. The neutralized mixture should be allowed toequilibrate for at least 12 hours and should be used for the AcceptanceUnder Pressure test within 96 hours thereafter. Before the Carbopolmixture is used, it should be stirred in the container at low speed(about 50 rpm) for about 1 minute to ensure the mixture is homogeneous.

Analog C should, if prepared correctly, have a “Hardness” value between55 and 65 grams. Hardness is measured using a Stevens-Farnell QTS-25Texture Analyzer, model 7113-5 kg, and associated software on anIntel-based machine having a 486 processor or higher. A ½ inch stainlesssteel spherical probe and an analog receptacle are provided. A suitableprobe is the TA18 probe available from Leonard Farnell Co. of Hatfield,England. The analog receptacle can be made by cutting a 7 milliliterlinear low density polyethylene scintillation vial (having an insidediameter of 0.55 inches+/− 0.005 inches) to a 15 millimeter length.Suitable vials are available from Kimble Glass Company of Vineland, N.J.as #58503-7 vials. The analog receptacle is filled to within 2millimeters of the top edge with the analog to be tested. The vial iscentered under the ½ inch spherical stainless steel probe. The probe islowered to a distance of about 1 millimeter from the surface of theanalog in the vial. The probe 162 is moved downward 7 millimeters at 100millimeters per minute and then stopped. The Hardness is the maximumrecorded resistive force encountered by the probe on its 7 millimeterstroke. (The temperature of the room and the analog should be betweenabout 65 to 75 degrees Fahrenheit during the course of the measurement.)

Sample Preparation Method

A 250 mL Precleaned VWRbrand TraceClean jar (VWR #15900-196) is placedon a balance and tared. The desired amount of chemical agent is measuredinto the cup and its exact weight is recorded. After the chemical weightis recorded the balance is tared again. The desired amount of feces orfecal analog is measured into the cup containing the chemical agent. Theexact amount of feces or fecal analog is recorded and the chemical agentand feces or fecal analog is stirred vigorously using the spatula end ofa Standard Ayre Cervi-Scraper (VWR #15620-009) until homogeneous (totalstirring time is generally about 2 minutes). For the purposes of thismethod, the beginning of the stirring process is defined as t=0 minutes.After the sample is mixed it is allowed to sit for the remainder of thedesired reaction time. For the data presented herein, this reaction timeis set at t=three minutes elapsed from the beginning of the stirringprocess. It is then loaded into the 16 mm receptacle described above inthe Hardness Method using the spatula end of a Standard AyreCrevi-Scraper, and the Hardness test is performed (starting at t=3 min.from the beginning of the stirring process, as described above).

Acceptance Under Pressure

Acceptance Under Pressure is measured by the following test which usesthe apparatus 139 illustrated in FIG. 9. A hollow plexiglas cylinder 140is provided mounted on a stainless steel plate 142 about 9.5 mm thick.The plate 142 is a square, about 10.16 cm×10.16 cm (about 4 in.×4 in.).The cylinder 140 and plate combination has a height of 7.6 centimeters(about 3.0 inches), an inside diameter of 5.08 centimeters (about 2.00inches) and an outside diameter of 6.3 centimeters (about 2.48 inches).The bottom of the cylinder 140 extends below the plate 142 a distance ofabout 3.5 millimeters. The lip 143 prevents the test fluid 166 fromleaking outside the designated test area. Two 625 gram weights 156 arealso provided, each having a diameter of 5.08 cm (about 2.0 inches).

A cylindrically shaped 24.6 gram plexiglas weight 144 is provided. Theweight 144 has a diameter of 5.08 centimeters (about 2.0 inches), sothat the weight 144 fits with close tolerance within the cylinder 140but can freely slide throughout the hole 141 in the cylinder 140. Thisarrangement provides a pressure of about 119 Pascals (Pa) (about 0.017pounds per square inch) and a test area of about 20.27 square cm (about3.142 square inches). If desired, the weight 144 may have a handle 145to allow it to be easily inserted into and removed from the cylinder140. In such cases, the combined mass of the handle 145 and thecylindrical weight 144 should equal 24.6 grams.

A sample 146 of the structure to be tested for Acceptance Under Pressureproperties is provided. The sample 146 may be cut from an existingdiaper or may be constructed from material which has not been formedinto a diaper. The sample 146 includes the entire structure intended foruse in an article or the entire structure of the article to beevaluated, including the top layer 161. (In order to measure theAcceptance Under Pressure performance of discrete acceptance elements,as described in the Acceptance Element section above, the AcceptanceUnder Pressure test is performed using a standard storage element 147 inplace of any underlying structure or layers. The standard storageelement 147 used herein includes a 4 inch square 1.6 mm thick aluminumplate having a pattern of 153 regularly spaced 4.3 mm diameter holes168, as shown in FIG. 10. The holes are arranged such that there areabout 26 holes per square inch.) The sample 146 should be cut into asquare measuring 10.16 centimeters by 10.16 centimeters (about 4 inchesby 4 inches).

Five layers of a high basis weight blotter 149 measuring 4 inches×4inches are provided. The top layer 161 of the sample 146 is removed andthe remaining components, or layers, of the sample 146 (if there aremultiple components or layers) and the five sheets of blotter material149 are weighed to the nearest 0.01 grams. Thus, if the sample 146 isbeing taken from a diaper, the layers of the diaper such as topsheets,secondary topsheets, acquisition layers, absorbent cores etc., should beseparated prior to weighing. (In some cases, a single layer may comprisetwo or more permanently bonded components.) In so doing, care must betaken not to destroy the sample 146 or cause unintended grossdeformation of any parts of the sample 146. The layers of the sample 146may be frozen to aid their separation from adjacent layers of the sample146. Freezing may be accomplished using PH100-15 circuit refrigerantmade by Philips ECG, Inc. of Waltham, Mass.

The sample 146 should be reassembled as originally configured on top of5 stacked layers of blotter material 149 with the side of the sample 146intended to face the wearer oriented facing up and away from the blottermaterial 149. The blotter material 149 is preferably filtration gradepaper, available from Ahlstrom Filtration, Inc. of Mt. Holly Springs,Pa. as #632-025, having a basis weight of about 90 grams per meter.

The combined assembly of the sample 146 and the blotter material 149 iscentered on the work surface 164 of a Stevens-Farnell QTS-25 Model7113-5 kg Texture Analyzer 160 (available from Leonard Farnell Co. ofHatfield, England), under the probe 162. A suitable probe 162 is a 100cm flat-ended cylindrical aluminum extension rod “QTSM3100” availablefrom the Leonard Farnell Co. of Hatfield England. The cylinder 140 iscentered on the sample 146. The two 625 gram weights 156 are placed onopposite corners (diagonally) of the plate 142 to stabilize it. Asyringe having an opening of about 4 to 6 millimeters is used todispense approximately 10 cubic centimeters of viscous fluid bodilywaste analog 166 (Analog C as described below) through the hole 141 inthe cylinder 140 onto the top of the sample 146.

Once the proper amount of feces analog 166 (Analog C) has been measuredinto the cylinder 140, the 24.6 gram weight 144 is inserted slowly andgently into the hole 140 in the cylinder 140 until it rests on thesurface of the analog, and subsequently gently rotated one rotationclockwise followed by one rotation counter-clockwise, both rotationsperformed while carefully avoiding the application of any downward forceon the weight. The Texture Analyzer 160 is activated so the probe 162depresses the cylindrical weight 144 at a rate of 10 millimeters perminute until a resisting force of about 144.6 grams is reached. TheTexture Analyzer 160 is set to stop the downward stroke once theresistance force of 144.6 grams is reached. The recorder is set totrigger at a resistive force of 5 grams. (The maximum resisting force of144.6 grams corresponds to an applied pressure of 700 Pascals or 0.1pounds per square inch). Once a resistive force of 144.6 grams isreached, the probe 162 is retracted to its starting position.

The weight 144 is removed from the cylinder 140, and then the cylinder140 is removed from the surface of the sample 146, taking care not todrip any Analog C remaining in the cylinder 140 onto the sample. The toplayer 161 of the sample 146 is then removed from the underlying layer(s)of the sample 146 by dragging the top layer 161 parallel to the surfaceof the underlying layers, if possible taking care not to drip any AnalogC onto the blotter paper. For certain structures where the top layer 161is difficult to remove by dragging parallel to the underlying layers,the top layer 161 may be peeled or lifted away from the underlyinglayers of sample 146. If the sample 146 comprises only a single layer,the standard acceptance element 151, described below, is utilized as thetop layer 161 of the sample 146. The underlying layers of the sample 146and the blotter material 149 are then weighed. The amount of test AnalogC accepted by the sample 146 equals the increase in combined weight ofthe underlying layer(s) of the sample 146 and the blotter material 149caused by the test Analog C penetrating through the top surface layer ofthe sample 146 per unit work performed (in milliJoules) on a unit areabasis. The area under the force vs. distance curve, used in calculatingthe unit work, is calculated by integrating the force resisting theprobe on its downward stroke over the total distance traveled until themaximum force of 144.6 grams is registered. The unit work is calculatedusing the following equation:Unit Work (mJ)=Area under the force vs. distance curve (g/mm) (9.81m/s²)/(1000 mm/m)Waste Contamination Area and Mass Methods

Waste Contamination Area and Mass are determined by the followingprocedures, certain of the assemblies and apparatus used in theprocedures being illustrated in FIGS. 13 through 20.

Preparation of Skin Assembly

As shown in FIG. 13, a skin assembly 201 is prepared from a skin analog203 and a backing sheet 205. The skin analog is a 10.2 by 12.7 cm (4 by5 inch) BIOCLUSIVE self-adhesive transparent dressing (hereinafter,BIOCLUSIVE film), available from Johnson & Johnson Medical of Arlington,Tex. The backing sheet is a 15.2 by 20.3 cm (6 by 8 inch) portion cutfrom black background paper (Epic BLACK CLASSIC linen paper, availablefrom Johnston Paper Company, Cincinnati, Ohio). The skin assembly isformed by carefully removing the outer wrapping and release paper fromthe BIOCLUSIVE film, centering the film on the backing sheet (with therespective long edges parallel), and then using the film's adhesive toaffix the film to the backing sheet. Care should be taken when affixingthe film to the backing sheet to leave as few film wrinkles as possible.If film wrinkles having a cumulative length of greater than about 2 cmare visible to the naked eye after affixation, that skin assembly shouldbe discarded and a new skin assembly prepared.

In cases where an article of the invention contains a lotion or otherskin care composition that transfers from the article to a portion ofthe wearer's skin as heretofore described (such as from a lotionedtopsheet of a diaper), the skin assembly should be modified by applyinga thin coating of the lotion or other skin care composition to the skinassembly to simulate a transfer of such a composition to a wearer's skinas may occur in vivo. In cases where the lotion or other skin carecomposition acts as a carrier for an additional composition, includingan agent such as an FMA, this additional composition/agent should becombined with the lotion or skin care composition as it would be in thearticle before the thin coating is applied. Otherwise, the procedure tomodify the skin assembly described in the immediately followingparagraph need not be performed, and the next step will be theapplication of Fluorescing fecal Analog B to the skin assembly.

To modify a skin assembly 201 with a lotion or skin care composition,skin assembly 201 is first weighed to the nearest 0.0001 gram and thisinitial weight recorded. The skin assembly is then placed on a papertowel on a flat surface such as a table with the black backing sheetfacing the towel. As shown in FIG. 14, a template 207, made by cutting a7.6 by 20.3 cm (3 by 8 inch) paper segment from the earlier describedblack background paper and then cutting a 5 by 13 cm (2 by 5 inch)rectangular opening in the center of the paper segment, is centered andplaced on the BIOCLUSIVE film 203 of skin assembly 201. A thin layer 209of the lotion or other skin care composition (combined with an addedcomposition/agent if the lotion or other skin care composition acts as acarrier for the added composition/agent) is deposited on the portion ofthe BIOCLUSIVE film 203 of skin assembly 201 which is exposed throughthe opening in template 207 so as to produce an substantially uniformlotion or other skin care composition layer covering substantially theentire exposed portion of the film. Such a thin layer may be deposited,for example, by rubbing a sample of the lotion or other skin carecomposition with the fingertips, and then rubbing the fingertips on theexposed portion of the BIOCLUSIVE film. Template 207 is removed and themodified skin assembly with the lotion or other skin care compositionapplied is weighed. The difference between modified skin assembly weightthe initial weight represents the amount of lotion or other skin carecomposition present on the skin assembly. If this amount is below 0.0045grams, then template 207 should again be placed on the skin assembly aspreviously described, additional lotion or other skin care compositionapplied, and the modified skin assembly reweighed until the amount isbetween 0.0045 grams and 0.0065 grams. If the amount exceeds 0.0065grams, the skin assembly should be discarded and the aforesaid procedurerecommenced until an assembly having an amount of lotion or other skincare composition falling within the specified range is obtained. Theskin assembly 201 is then stored in an incubator (e.g., Labeline Model120, available from Labeline Instruments Inc. of Melrose Park, Ill.) at38-39 degrees centigrade for one hour, in a manner which does not allowlotion to transfer from the assembly, to bring the assembly to humanbody temperature. This may decrease the viscosity of the lotion or otherskin care composition, and allow formation of a more even layer oflotion or other composition on the BIOCLUSIVE film. Prior to applicationof a fluorescing fecal analog, as described below, skin assembly 201 isremoved from the incubator.

As shown in FIG. 15, Fluorescing Analog B (described above) 211 isdisposed on a portion of the exposed BIOCLUSIVE film 203 (which mayinclude the thin layer 209 described in the preceding paragraph) of skinassembly 201 using a REPLICA R120 self-adhesive locating ring 213available from CuDerm Corp. of Dallas, Tex. With its release paperremoved, locating ring 213 is placed adhesive side down on the exposedBIOCLUSIVE film 203 of skin assembly 201 with the outer edge of the ringtangentially aligned with an exposed transverse edge 215 of the film.Using a wood or metal spatula, the interior of locating ring 213 isoverfilled with Fluorescing Analog B. Excess analog is scraped off tolevel the analog with the top of locating ring 213, taking care not todeposit any of the analog on the film outside the interior of the ring.Locating ring 213 is carefully removed from the skin assembly, leaving alevel column of Fluorescing Analog B 211 approximately 19 mm in diameterand 1.1 mm in height.

In cases where an article of the invention contains a composition,including an agent such as an FMA, which is capable of transferring tothe wearer's skin or bodily waste through means independent of anylotion or other skin care composition carrier, then the proceduredescribed in the immediately following paragraph to add such acomposition/agent to the skin assembly 201 prepared with FluorescingAnalog B 211 described above should be performed. If such an independentcomposition and/or agent is not present, the procedure described in theimmediately following paragraph should not be performed, and the nextstep will be the performance of the wiping test.

To add a composition such as an FMA to skin assembly 201, the skinassembly is placed on a paper towel on a flat surface such as a tablewith black backing sheet 205 facing the towel. An agent template 217,made by cutting a 15.2 by 20.3 cm (6 by 8 inch) paper segment from theblack background paper described above and then cutting a 5 by 13 cm (2by 5 inch) rectangular opening in the center of the paper segment, iscentered and placed on the BIOCLUSIVE film 203 of skin assembly 201. Amass of 0.5 grams of the composition/agent, shown as element 219 in FIG.16, is substantially uniformly distributed onto the portion of theBIOCLUSIVE film of skin assembly 201 which is exposed through theopening in agent template 217, as well as onto Fluorescing Analog B 211,so as to cover substantially the entire exposed portion of the film andfluorescing analog. Depending on the form of the composition/agent, thecomposition/agent may be uniformly distributed using any appropriatemeans known to one skilled in the art. For example, and withoutlimitation, compositions/agents that are in powder form may be siftedonto the film through a strainer; those having a liquid form may besprayed onto the film; and those having a higher viscosity may bemanually rubbed onto the film as described above in connection withlotions or other skin care compositions. After distribution of thecomposition/agent, the agent template 217 is carefully removed.

Although the foregoing procedure is described in connection with thepreparation of a single skin assembly, it should be understood that theprocedures can be repeated to prepare additional skin assemblies. Asdescribed below, at least six assemblies of the same composition shouldbe prepared and analyzed to ensure that reliable data has been obtained.

Wiping Test

As soon as an appropriate skin assembly or assemblies are prepared asdescribed above, the skin assemblies are subjected to a wiping test. Thewiping test utilizes a wiping sled 221, as shown in FIGS. 17-19. Sled221 has a flat bottom surface 223 having a transverse dimension T of12.7 cm (5 inches), and side edges 225 having a longitudinal dimension Lextending 12.7 cm (5 inches). As shown in FIG. 17, the front 227 of sled221 curves upwardly from flat bottom surface 223, the curve having aradius of 1.6 cm (0.62 inches) and extending from sled side edge to sideedge. As shown in FIG. 18, the front 227 of sled 221 also includes atransversely-extending concavity 229 having a radius of 12.7 cm (5inches). Sled 221 may be made of aluminum or other suitable material sothat the flat bottom surface of the sled (when the sled includes aclamping bar and wipe described below) applies a substantially uniformdownward pressure of 0.324 kPa (0.047 psi) when placed on a flathorizontal surface such as a table top. As will be recognized by oneskilled in the art, a weight or weights can be appropriately added tosled 221 so that the specified uniform pressure is applied. A pull line231 is attached to a harness 233 attached to each side edge of 225 ofsled 221. Pull line 231 extends to any suitable pulling apparatus 235(such as a motorized drive that winds the pull line) capable of pullingsled 221 (along with the wipe described below) linearly over skinassembly 201 at a substantially constant speed of 17 cm per second.

The wiping test also utilizes a fresh wipe provided from a package ofPAMPERS BABY FRESH wipes (unscented, alcohol fee, with moisture pillows;available from The Procter & Gamble Company, Cincinnati, Ohio) or anequivalent wipe. A method of making such a PAMPERS BABY FRESH wipe isdisclosed, modified as described below, in the Example set forth in U.S.application Ser. No. 08/915,349 entitled “Disposable Premoistened WipeHaving Opacity Agent”, filed Aug. 22, 1997 in the name of Gorely, whichapplication is incorporated herein by reference. The Example in theaforesaid application is modified to make the PAMPERS BABY FRESH wipereferenced above by including about 76.4 percent cellulosic fibers, 12.9percent polyester fibers, and 10.7 percent adhesive binder (the bindercontains no titanium dioxide) in the substrate web. The web is embossedusing the pattern described below, with an embossing roll having a landarea of about 18 percent. The amount of binder adhesive sprayed on theweb is sufficient to provide a dry web having about 10.7 percent by dryweight binder adhesive solids. As indicated in the aforesaid Example,the web is premoistened with a liquid composition comprising about 97%water, with the remaining 3% being the other listed minor constituents.The embossing pattern for the PAMPERS BABY FRESH wipe is depicted inU.S. Design Pat. No. 400,716, issued Nov. 10, 1998, which is alsoincorporated herein by reference, the wipe having an embossing patternrepeat of 16.0 cm (6.3 inches), the character line thickness being 0.081cm (0.032 inches), and the ellipses having a major diameter of 0.28 cm(0.11 inches) and minor diameter of 0.14 cm (0.055 inches).

The wipe described above is cut along its longitudinal axis into a wipesegment 237 approximately 10.8 cm wide by 17.8 cm long (4.25 by 7inches). As shown in FIG. 19, wipe segment 237 is affixed to sled 221using a transversely-extending plastic clamping bar 239 (which may beheld in place by set screws 240) so that the wipe segment is centeredtransversely on sled 221 and extends from clamping bar 239 to terminateat the sled rear edge 241.

As further shown in FIG. 19, skin assembly 201 is attached to flathorizontal surface 243, such as a table top, with the backing paperfacing down and centered in front of sled 221. The end of the skinassembly on which Fluorescing Analog B 211 is disposed is orientedtoward the front 227 of sled 221, and the transverse edges of the skinassembly are oriented perpendicular to the direction in which the sledwill be pulled. Prior to the sled pull described below, the distancebetween the sled front 227 and the Analog 211 should not exceed about 15cm (5.9 inches) to ensure that wipe segment 237 does not lose excessivemoisture during the pull, prior to contacting the Analog 211. Theattachment of skin assembly 201 to flat surface 243 must be sufficientto prevent displacement of the skin assembly during the wiping test.Suitable attachment may be made using a piece of masking tape extendingtransversely over the edge of the skin assembly closest to sled 221 suchthat half of the tape width is firmly adhered to the backing and theremainder firmly adhered to the flat surface.

The wiping test is performed by employing pulling apparatus 235, pullline 231 and harness 233 to pull sled 221 and the affixed wipe segment237 linearly over skin assembly 201 at a substantially constant speed of17 cm per second, with the transverse centerline of sled 221 inalignment with the transverse centerline of the skin assembly 201 duringthe pull. Sled 221 is stopped after it clears the skin assembly. Thewiped skin assembly is labeled appropriately, and placed aside to dryfor 8 hours at about 21 degrees centigrade and about 53 percent relativehumidity before being analyzed using the image capture and analysisprocedure described below.

Image Capture and Analysis Apparatus

The image capture and analysis apparatus includes a Sony 3-CCD modelDXC-9000 progressive scanning color camera with an attached Fuji 7.5-105mm zoom video lens model VCL714BCEA. The camera is mounted to a BeselerBECS-21 copy stand available from the Beseler Co. of Linden, N.J., withthe lens facing downward and centered on a grid marked on the copy standbase. The video output from the camera is fed to both a VCR (videocassette recorder)/VCR monitor (e.g., Panasonic PV-M2048 VCR/monitoravailable from Panasonic Co., Secaucus, N.J.) and to a video interface(Ultra II framegrabber available from CORECO of Quebec, Canada having a2 MB display controller and image buffer, and an RGB acquisition module)installed in an IBM-PC compatible computer system having an Intel 486processor or higher. OPTIMAS version 6.21.19 Image Analysis softwareavailable from Media Cybernetics of Silver Springs, Md., and MicrosoftEXCEL version 7.0a spreadsheet software available from MicrosoftCorporation, Olympia, Wash., are also installed on the computer system.

The image capture and analysis apparatus also includes an ultraviolet(UV) light illumination system. The UV illumination system comprises two35.6 cm (14 inch) F8T5 linear light fixtures (with the diffusersremoved) with 25 kHz ballast from Stocker and Yale Inc. of Salem, N.H.,each fixture containing two Sylvania 8W BlacklightBlue FBW/BLB bulbs(peak wavelength 356 nm) and is attached to a frame. The frame ispositioned on the copy stand base so that a skin assembly centered onthe copy stand base grid will be centered transversely andlongitudinally relative to the UV bulbs. The frame is constructed so asto position the bulbs approximately 10 cm (4 inches) above the copystand base and to separate the light fixtures transversely from oneanother by approximately 20 cm (8 inches). Each light fixture is rotatedaround its major axis (at about a 45 degree angle) so that each fixturefocuses the light toward the center of the copy stand base.

Camera Focusing and Brightness Calibration

A dried skin assembly containing the fluorescing fecal analog is used toprovide a baseline image with which to set the camera focus and zoom.The skin assembly is centered on the copy stand grid, backing sheetdown, under the activated UV lights, and the room is otherwise darkened.With the camera, computer and TV monitor on, the camera iris is openedto its maximum to yield a bright image. The camera is then focused andthe lens zoom adjusted until the largest image of the BIOCLUSIVE film ofthe skin assembly can be seen on the VCR monitor and the to computerscreen, with the fluorescing portion in focus. The skin assembly is thenremoved. The camera focus and zoom will remain at these settings for theremainder of the image capturing session.

A UV calibration is then made to verify that the UV lights are providingthe desired illumination. Using a Heavy Duty Ultraviolet Light MeterModel No. 40736A (UVA) (available from Extech Instruments of Waltham,Mass.), UV readings are taken at the center of the copy stand grid, andat two other locations on the grid which are each about 2.5 inchesdirectly toward a respective light fixture from the grid center (i.e.,one reading on each side of the center). If any of the readings arebelow about 0.25 milliwatts/cm², one or more of the UV bulbs must bechanged.

Skin Assembly Image Capture

An ROI (region of interest) template 245, made by cutting a 7.6 by 20.3cm (3 by 8 inch) paper segment from the earlier described blackbackground paper and then cutting a 3 by 13 cm (1.2 by 5 inch)rectangular opening in the center of the paper segment, is provided asshown in FIG. 20. White marks 247 are made on the template directlyadjacent each corner of the rectangular opening so that the marks willappear in a captured image and be used to establish a consistently-sizedROI. Each skin assembly to be analyzed is centered on the copy standgrid, backing sheet down, with the UV illumination system activated. Asalso shown in FIG. 20, the ROI template 245 is placed over the smear 251of Fluorescing Analog B 211, with the smear centered transversely in therectangular opening and so that a transverse edge 253 of the rectangularopening is aligned with the edge 215 of the BIOCLUSIVE film (i.e., theedge adjacent to the earlier applied fluorescing fecal analog column).Using OPTIMAS, an image of this arrangement captured and saved as anappropriately identified TIFF file on the computer. The process isrepeated for each skin assembly to be analyzed.

After images of all the skin assemblies are captured and saved, the UVillumination is turned off and the room once again illuminated normally.A ruler is placed on the copy stand in the center of the copy stand gridand an its image is captured and saved as the distance calibrationreference image in an 8 bit TIFF RGB format (all images are saved inthis TIFF format).

Image Analysis

Using OPTIMAS, the distance calibration reference image is opened todevelop a distance calibration for the skin assembly images. MicrosoftEXCEL is then run and a new spreadsheet opened. Returning to OPTIMAS,the Area Morphometry Data Collection Set is selected. The Set is editedif necessary by removing all of the measurements except mArArea (area insquare calibrated units of a area object), and by adding the measurementmArGV (mean scaled luminance of pixels within an area boundary).Microsoft EXCEL is selected as the export data file and linked to thenew spreadsheet called [Book1]Sheet1. In OPTIMAS, the desired skinassembly image file is then opened and a rectangular ROI is drawn tocorrespond to the rectangular opening of the ROI template appearing inthe skin assembly image, using the ROI template reference marks as anaid for locating the corners of the rectangular opening. The bluechannel is then selected which maximizes the contrast between thefluorescent analog smear and the background. The upper mean brightnessthreshold limit is set to 174. Then the area sampling parameters areadjusted by changing the minimum boundary length to 2, hole treatment to“ignore all holes”, and boundaries to “on surrounding pixel center”. TheOPTIMAS software is then instructed to identify the areas of fluorescingfecal analog having a mean brightness exceeding the upper meanbrightness threshold limit. The distance calibration is then changed tothe calibration based on the distance calibration reference image.OPTIMAS is then instructed to make mArArea and mArGV measurements fromthe skin assembly image, which are exported to the active spreadsheet[Book1]Sheet1. The measurement set spreadsheet is then named inMicrosoft EXCEL consistently with the skin assembly measured, and thespreadsheet is saved on the computer. The foregoing process is repeatedfor each skin assembly image to be analyzed.

Calculations

The area of fluorescing fecal analog remaining on the skin assemblyafter wiping is determined from the measured value of each mArArea incm². Waste Contamination Area is calculated by summing all the mArAreavalues for the particular skin assembly analyzed, and then calculatingthe arithmetic mean of the sums obtained from the skin assembliesanalyzed that are of the same composition. As described above, at leastsix skin assemblies should be analyzed.

The mass of fluorescing fecal analog remaining on the skin assemblyafter wiping is calculated from the equation (mArArea×mArGV)/255, wheremArGV corresponds to the mean brightness of the pixels bounded by eacharea (i.e., the intensity of the fluorescence of the residual fecalanalog remaining in each mArArea) and where the minimum brightness valueis 0 and maximum is 255. In instances where the fecal analog remainingin an area has more than a certain thickness, a brightness value of 255will always be measured and it is recognized that the mass of a thickarea of remaining analog will be calculated as less than actual. WasteContamination Mass, which is expressed in mass units, is calculated bysumming all the (mArArea×mArGV)/255 values for the particular skinassembly analyzed, and then calculating the arithmetic mean of the sumsobtained from the skin assemblies analyzed that are of the samecomposition.

Below is a sample table of OPTIMAS measurements obtained from analyzinga particular skin assembly, in an EXCEL spreadsheet with calculationcolumns.

(mArArea X mArGV)/ Area Label mArArea cm² mArGV 255 mass units L0: 0.03213.4 0.03 L1: 3.00 244.7 2.88 L2: 0.02 226.7 0.02 L3: 0.00 175.3 0.00L4: 0.01 175.9 0.00 L5: 0.00 182.5 0.00 L6: 0.00 177.0 0.00 L7: 0.01200.9 0.01 L8: 0.01 199.1 0.01 L9: 0.00 182.0 0.00 L10: 0.01 191.9 0.01L11: 0.00 186.6 0.00 L12: 1.97 238.4 1.84 L13: 0.01 188.9 0.01 L14. 0.01202.7 0.01 L15: 0.01 195.3 0.00 L16: 0.02 219.4 0.01 L17: 0.04 221.20.04 L18: 0.00 176.5 0.00 L19: 0.01 205.9 0.01 L20: 0.01 193.3 0.00 L21:0.01 211.5 0.01 L22: 0.00 178.0 0.00 L23: 0.00 188.3 0.00 L24: 0.01213.2 0.01 L25: 0.39 188.5 0.29 L26: 0.02 181.5 0.01 L27: 0.03 182.90.02 L28: 0.02 220.1 0.01${\overset{L\; n}{\sum\limits_{L\; 0}}{mArArea}} = {\text{5.65}{cm}^{2}}$$\quad\begin{matrix}{\overset{L\; n}{\sum\limits_{L\; 0}}{\left( {{mArArea}\; X\mspace{14mu}{mArGV}} \right)/}} \\{\mspace{45mu}{255 = \text{5.24 mass units}}}\end{matrix}$Waste Contamination Area=mean of

$\sum\limits_{L\; 0}^{Ln}$mArArea for n≧6 assembliesWaste Contamination Mass=mean of

$\sum\limits_{L\; 0}^{Ln}$(mArArea×mArGV)/255 for n≧6 assemblies

While particular embodiments and/or individual features of the presentinvention have been illustrated and described, it would be obvious tothose skilled in the art that various other changes and modificationscan be made without departing from the spirit and scope of theinvention. Further, it should be apparent that all combinations of suchembodiments and features are possible and can result in preferredexecutions of the invention. Therefore, the appended claims are intendedto cover all such changes and modifications that are within the scope ofthis invention.

1. A disposable article adapted to be worn by a wearer comprising: adiaper comprising a topsheet connected with a backsheet, and anabsorbent core disposed between the backsheet and topsheet; one or morecompositions for enhancing removability of fecal waste from skin of thewearer, said one or more compositions stored within the diaper prior tothe diaper being first used and prior to a first excretion of fecalwaste from the wearer and being available to at least a portion of oneof said fecal waste and said skin of said wearer; and wherein the diapercomprises a responsive system disposed within the diaper so as to belocated between the backsheet and the wearer, the responsive systemincluding a sensor and an actuator, the sensor adapted to detect aninput, and the actuator being adapted to deliver said one or morecompositions to at least a portion of said fecal waste excreted fromsaid wearer when the sensor detects the input, and said one or morecompositions provide one or more of the following as determined by testmethods set forth in the specification: a) a Waste Contamination Area ofless than about 15 cm²; b) a Waste Contamination Mass calculated from anequation $\sum\limits_{L\; 0}^{Ln}$ (mArArea×mARGV)/255 of less thanabout 14 mass units.
 2. The disposable article of claim 1 wherein saidone or more compositions provide a Waste Contamination Area of less thanabout 12 cm².
 3. The disposable article of claim 2 wherein said one ormore compositions provide a Waste Contamination Area of less than about10 cm².
 4. The disposable article of claim 2 wherein said one or morecompositions provide a Waste Contamination Mass calculated from theequation $\sum\limits_{L\; 0}^{Ln}$ (mArArea×mArGV)/255 of less thanabout 10 mass units.
 5. The disposable article of claim 4 wherein saidone or more compositions provide a Waste Contamination Mass calculatedfrom the equation $\sum\limits_{L\; 0}^{Ln}$ (mArArea×mArGV)/255 of lessthan about 8 mass units.
 6. The disposable article of claim 1 wherein atleast one of said compositions comprises an effective concentration of afeces modifying agent.
 7. The disposable article of claim 6 wherein atleast one of said compositions comprises a skin care composition.
 8. Thedisposable article of claim 1 comprising a skin care composition on awearer-contacting surface.
 9. The disposable article of claim 7 or 8wherein said skin care composition comprises a material selected fromthe group consisting of: petroleum oils, petroleum waxes, silicone oils,and silicone waxes.
 10. The disposable article of claim 6 wherein thefeces modifying agent includes a viscosity increasing agent.
 11. Thedisposable article of claim 10 wherein the viscosity increasing agentincludes a thickener.
 12. The disposable article of claim 11 wherein thethickener is selected from the group consisting of: carboxymethylcellulose, xanthan gum, polyacrylic acid and salts thereof,polyacrylamide, and polyethyleneimines.
 13. The disposable article ofclaim 10 wherein the viscosity increasing agent includes an ioniccomplexing agent.
 14. The disposable article of claim 13 wherein theionic complexing agent is selected from the group consisting of: ZnO,MgO, MnO, CaO, calcium hydroxide, ethanolamines, quaternary ammoniumsalts, Al2O3, alginates, zinc salts, aluminum salts and combinationsthereof.
 15. The disposable article of claim 6 wherein said fecesmodifying agent is disposed in the article as an individual discreteelement.
 16. The disposable article of claim 6 wherein said fecesmodifying agent is associated with a carrier structure which includes acomponent selected from the group consisting of: a web of material, afilm, a fibrous structure, a loop material, a brush structure, and astructure which releasably encapsulates said feces modifying agent. 17.The disposable article of claim 1, wherein the one or more compositionsis joined to the diaper while the one or more compositions is beingstored.
 18. The disposable article of claim 1, wherein the diaperfurther comprises a leg cuff, and the one or more compositions isattached to the leg cuff while the one or more compositions is beingstored.
 19. The disposable article of claim 1, wherein the one or morecompositions is attached to the topsheet while the one or morecompositions is being stored.
 20. A method of enhancing removability ofbodily waste from the skin of a wearer of a disposable article, themethod comprising: providing a diaper comprising a topsheet connectedwith a backsheet, and an absorbent core disposed between the backsheetand topsheet, the diaper adapted to be worn by the wearer; storing oneor more compositions for enhancing the removability of fecal waste fromskin of the wearer within the diaper prior to the diaper being firstused and prior to a first excretion of fecal waste by the wearer so thatsaid one or more compositions are available to at least a portion of oneof said bodily waste and said skin of said wearer and wherein the diapercomprises a responsive system disposed within the diaper so as to belocated between the backsheet and the wearer, the responsive systemincluding a sensor and an actuator, the sensor adapted to detect aninput, and the actuator being adapted to deliver said one or morecompositions to at least a portion of said fecal waste excreted fromsaid wearer when the sensor detects the input; said one or morecompositions providing one or more of the following as determined by thetest methods set forth in the specification: a) a Waste ContaminationArea of less than about 15 cm²; b) a Waste Contamination Mass calculatedfrom equation $\sum\limits_{L\; 0}^{Ln}$ (mArArea×mArGV)/255 of lessthan about 14 mass unit.
 21. The method of claim 20 wherein at least oneof said compositions comprises an effective amount of a feces modifyingagent.
 22. The method of claim 21 wherein at least one of saidcompositions comprises a skin care composition.